The mechanical properties of polycrystalline materials are largely determined by the kinetics of the phase transformations during the production process. Progress in x-ray diffraction instrumentation at synchrotron sources has created an opportunity to study the transformation kinetics at the level of individual grains. Our measurements show that the activation energy for grain nucleation is at least two orders of magnitude smaller than that predicted by thermodynamic models. The observed growth curves of the newly formed grains confirm the parabolic growth model but also show three fundamentally different types of growth. Insight into the grain nucleation and growth mechanisms during phase transformations contributes to the development of materials with optimal mechanical properties.

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Partitioning at phase boundaries of complex steels is important for their properties. We present atom probe tomography results across martensite / austenite interfaces in a precipitation-hardened maraging TRIP steel (12.2 Mn, 1.9 Ni, 0.6 Mo, 1.2 Ti, 0.3 Al; at.%). The system reveals compositional changes at the phase boundaries: Mn and Ni are enriched while Ti, Al, Mo, and Fe are depleted. More specific, we observe up to 27 at.% Mn in a 20 nm layer at the phase boundary. This is explained by the large difference in diffusivity between martensite and austenite. The high diffusivity in martensite leads to a Mn-flux towards the retained austenite. The low diffusivity in the austenite does not allow accommodation of this flux. Consequently, the austenite grows with a Mn-composition given by local equilibrium. The interpretation is based on DICTRA and mixed-mode diffusion calculations (using a finite interface mobility).

In situ three-dimensional (3-D) X-ray diffraction experiments have been performed at a synchrotron source on low-alloyed multiphase TRIP steels containing 0.25 wt.% Si and 0.44 wt.% Al and produced with different bainitic holding times, in order to assess the influence of the bainitic transformation on the thermal stability of individual austenite grains with respect to their martensitic transformation. A detailed characterization of the austenite grain volume distribution at room temperature was performed as a function of the prior bainitic holding time. In addition, the martensitic transformation behaviour of individual metastable grains was studied in situ during cooling to a temperature of 100 K. Both the carbon content and the grain volume play a key role in the stability of the austenite grains below 15 lm 3 , while the carbon content exerts the dominant effect in the stability of the bigger grains. Measurements also suggest that the tetragonality of the thermally formed martensite is suppressed.

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Using a new approach to modeling bainite nucleation, the kinetics of isothermal bainite formation have been calculated under the assumption of displacive growth. The nucleation rate is assumed to depend on the number density of potential nucleation sites Ni, a factor λ accounting for autocatalytic nucleation, and an activation energy Q*. Compatible with the theory for athermal martensite nucleation, Ni is assumed to be proportional to the driving pressure. Analogous to the Koistinen – Marburger model for martensite formation, the average volume of bainitic sub-units is assumed to be constant over the extent of the transformation and the growth of sub-units is very fast, and thus the change in fraction is directly related to the nucleation rate of bainite. The model results in an analytical expression for the fraction bainite as a function of time that contains only two adjustable parameters: a (temperature independent) autocatalytic parameter λ and a rate parameter κ, which has a temperature dependence that is mainly governed by Q*. The calculations are compared with experimental fraction curves measured isothermally with dilatometry for the carbon steels C45, C50 and C60 at a range of temperatures. From the best agreement between the calculations and the experimental data it follows that Q* decreases linearly with temperature, which is consistent with other bainite nucleation models. By austenitizing steel C60 at different temperatures it is found that λ depends on the austenite grain size: when the austenite grain size is increased, λ becomes larger.