We propose all-dielectric metasurfaces that can be actively re-configured using the phase-change material Ge 2 Sb 2 Te 5 (GST) alloy. With selectively controlled phase transitions on the composing GST elements, metasurfaces can be tailored to exhibit varied functionalities. Using phase-change GST rod as the basic building block, we have modelled metamolecules with tunable optical response when phase change occurs on select constituent GST rods. Tunable gradient metasurfaces can be realized with variable supercell period consisting of different patterns of the GST rods in their amorphous and crystalline states. Simulation results indicate a range of functions can be delivered, including multilevel signal modulating, near-field coupling of GST rods, and anomalous reflection angle controlling. This work opens up a new space in exploring active meta-devices with broader applications that cannot be achieved in their passive counterparts with permanent properties once fabricated.
Abstract. The frequency of dry-season droughts and wet-season storms has been predicted to increase in subtropical areas in the coming decades. Since subtropical forest soils are significant sources of N2O and NO3−, it is important to understand the features and determinants of N transformation responses to the predicted precipitation changes. A precipitation manipulation field experiment was conducted in a subtropical forest to reduce dry-season precipitation and increase wet-season precipitation, with annual precipitation unchanged. Net N mineralization, net nitrification, N2O emission, nitrifying (bacterial and archaeal amoA) and denitrifying (nirK, nirS and nosZ) gene abundance, microbial biomass carbon (MBC), extractable organic carbon (EOC), NO3−, NH4+ and soil water content (SWC) were monitored to characterize and explain soil N transformation responses. Dry-season precipitation reduction decreased net nitrification and N mineralization rates by 13–20 %, while wet-season precipitation addition increased both rates by 50 %. More than 20 % of the total variation of net nitrification and N mineralization could be explained by microbial abundance and SWC. Notably, archaeal amoA abundance showed the strongest correlation with net N transformation rates (r ≥ 0.35), suggesting the critical role of archaeal amoA abundance in determining N transformations. Increased net nitrification in the wet season, together with large precipitation events, caused substantial NO3− losses via leaching. However, N2O emission decreased moderately in both dry and wet seasons due to changes in nosZ gene abundance, MBC, net nitrification and SWC (decreased by 10–21 %). We conclude that reducing dry-season precipitation and increasing wet-season precipitation affect soil N transformations through altering functional microbial abundance and MBC, which are further affected by changes in EOC and NH4+ availabilities.
The mechanism and control of ferroelectric polarization fatigue (loss of polarization with cycling) in donor- and acceptor-doped BaTiO3 ceramics and Pb(Zr1−xTix)O3 (PZT) thin films has been investigated. Experimental results clearly demonstrate that fatigue behavior is related to the defects within the materials. Donor-doped BaTiO3 ceramics showed significantly improved fatigue characteristics when compared with acceptor-doped materials. A similar but reduced effect has been observed in donor-doped PZT thin films. The electric-field-assisted migration of charged species within ferroelectric materials may be responsible for the degradation/fatigue behavior. Results support the expectation that oxygen vacancies play an important role in fatigue that occurs as a result of polarization switching.
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