For a hydrogel coating on a substrate to be stable, covalent bonds polymerize monomer units into polymer chains, crosslink the polymer chains into a polymer network, and interlink the polymer network to the substrate. In existing methods of hydrogel coating, the three processespolymerization, crosslinking, and interlinking-usually concur. This concurrency is unnecessary and hinders the widespread applications. In particular, many hydrogels are made by free-radical polymerization, involving toxic monomers, toxic initiators, and oxygen-free environment. For example, in the free-radical polymerization of a covalently crosslinked polyacrylamide hydrogel, when subject to UV light, the vinyl groups of acrylamide monomer and N,N′-methylenebisacrylamide crosslinker are activated concurrently. The former results in polyacrylamide chains and the latter results in a polyacrylamide network. When the substrate is involved, polymerization of monomers, crosslinking of poly mer chains, and interlinking between the hydrogel and substrate proceed concurrently. Since free radical polymerization is sensitive to oxygen, molding is usually required. Besides, molding is also used to control the shape and thickness of hydrogel coating. Depending on the geometry of the substrate, coating can be technically challenging for highly curved surfaces (e.g., 1D structures), or even impossible for hollow or cage structures. Furthermore, the monomers (e.g., acrylamide, acrylic acid, etc.) are usually toxic. Consequently, free-radical polymerization is unsuitable for everyday operation.For a hydrogel coating on a substrate to be stable, covalent bonds poly merize monomer units into polymer chains, crosslink the polymer chains into a polymer network, and interlink the polymer network to the substrate. The three processes-polymerization, crosslinking, and interlinking-usually concur. This concurrency hinders widespread applications of hydrogel coatings. Here a principle is described to create hydrogel paints that decouple polymerization from crosslinking and interlinking. Like a common paint, a hydrogel paint divides the labor between the paint maker and the paint user. The paint maker formulates the hydrogel paint by copolymerizing monomer units and coupling agents into polymer chains, but does not crosslink them. The paint user applies the paint on various materials (elastomer, plastic, glass, ceramic, or metal), and by various operations (brush, cast, dip, spin, or spray). During cure, the coupling agents crosslink the polymer chains into a network and interlink the polymer network to the substrate. As an example, hydrogels with thickness in the range of 2-20 µm are dip coated on medical nitinol wires. The coated wires reduce friction by eightfold, and remain stable over 50 test cycles. Also demonstrated are several proofofconcept applica tions, including stimuliresponsive structures and antifouling model boats.A hydrogel-coated substrate unites the superior properties of the substrate (e.g., strength, stiffness, and toughness) and the superior p...
The construction of multiple helicenes, one of important branches to curved polyaromatic hydrocarbons (PAHs) is a fundamental goal in both helicence chemistry and supramolecular chemistry. Here, we demonstrate the facile...
In article number 1903062, Zhigang Suo and co‐workers report a principle to develop green hydrogel paint based on decoupling of the synthesis and cure processes. As a result, after being manufactured in a factory, the paint product can be used to create hydrogel coatings by anyone. Such a principle re‐opens numerous ways to use hydrogel coatings in education, engineering, and medicine.
A series of linear acenes with five fused rings, which contain thiophene, selenophene, and tellurophene as the outmost rings, have been synthesized from well-known benzodithiophene (BDT). It was found that the optical, electrochemical properties and crystal packing motifs could be modulated by changing heteroatoms in the outmost rings.
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