Conformally carbon-coated FeP (FeP@C) nanoplates with abundant inner mesopores exhibit an extremely superior electrochemical performance for lithium-ion batteries.
Soft
carbon is attracting tremendous attention as a promising anode
material for potassium-ion batteries (PIBs) because of its graphitizable
structure and adjustable interlayer distance. Herein, nitrogen/sulfur
dual-doped porous soft carbon nanosheets (NSC) have been prepared
with coal tar pitch as carbon precursors in an appropriate molten
salt medium. The molten salt medium and N/S dual-doping are responsible
for the formation of nanosheet-like morphology, abundant microporous
channels with a high surface area of 436 m2 g–1, expanded interlamellar spacing of 0.378 nm, and enormous defect-induced
active sites. These structural features are crucial for boosting potassium-ion
storage performance, endowing the NSC to deliver a high potassiation
storage capacity of 359 mAh g–1 at 100 mA g–1 and 115 mAh g–1 at 5.0 A g–1, and retaining 92.4% capacity retention at 1.0 A
g–1 after 1000 cycles. More importantly, the pre-intercalation
of K atom from the molten salts helps improve the initial Coulombic
efficiency to 50%, which outperforms those of the recently reported
carbon anode materials with large surface areas. The density functional
theory calculations further illuminate that the N/S dual-doping can
facilitate the adsorption of K-ion in carbon materials and decrease
the ion diffusion energy barrier during the solid-state charge migration.
Two types of activated carbons have been prepared by HPO activation of lignocellulose and by HPO modification of activated carbon, and then heat-treated at temperatures from 400 to 900 °C in an atmosphere of N or H to investigate the evolution of phosphorus-containing groups. Elemental analysis, X-ray photoelectron spectroscopy, P nuclear magnetic resonance, nitrogen adsorption, and scanning electron microscopy have been used to analyze the physicochemical properties of the activated carbons. The results show that C-O-P linkages of phosphorus-containing groups can progressively evolve into C-P-O, C-P═O, C-P, and eventually elemental phosphorus as a result of heat treatment. Phosphate-like groups are much more thermally stable in an N than in an H atmosphere. In N, C-O-P linkages significantly evolve into C-P-O and C-P═O at up to 800 °C, whereas C-P linkages are not formed even at 900 °C. In H, the corresponding evolution remarkably occurs at 500 °C, forming C-P linkages and eventually elemental phosphorus. Moreover, the two activated carbons exhibit different evolution trends, suggesting that the evolution happens more easily for phosphorus-containing groups located on the edges of graphite-like crystallites than those in the lattice. Finally, we propose different evolution pathways of phosphorus-containing groups upon heat treatment in N and H atmospheres.
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