Soft carbon is attracting tremendous attention as a promising anode material for potassium-ion batteries (PIBs) because of its graphitizable structure and adjustable interlayer distance. Herein, nitrogen/sulfur dual-doped porous soft carbon nanosheets (NSC) have been prepared with coal tar pitch as carbon precursors in an appropriate molten salt medium. The molten salt medium and N/S dual-doping are responsible for the formation of nanosheet-like morphology, abundant microporous channels with a high surface area of 436 m2 g–1, expanded interlamellar spacing of 0.378 nm, and enormous defect-induced active sites. These structural features are crucial for boosting potassium-ion storage performance, endowing the NSC to deliver a high potassiation storage capacity of 359 mAh g–1 at 100 mA g–1 and 115 mAh g–1 at 5.0 A g–1, and retaining 92.4% capacity retention at 1.0 A g–1 after 1000 cycles. More importantly, the pre-intercalation of K atom from the molten salts helps improve the initial Coulombic efficiency to 50%, which outperforms those of the recently reported carbon anode materials with large surface areas. The density functional theory calculations further illuminate that the N/S dual-doping can facilitate the adsorption of K-ion in carbon materials and decrease the ion diffusion energy barrier during the solid-state charge migration.

A three-dimensional numerical model for thermal-fluid-metallurgical coupling was established to inspect the effect from a stable longitudinal magnetic field on molten pool of magnesium/aluminum laser welding. Magnetic field-assisted laser welding platform was built to test the morphology and spectrum of the metal vapor/plasma. The scanning electron microscope (SEM) and energy dispersive spectrometry (EDS) were used to determine the morphology and element distribution of molten pool cross section. Simulation results showed that temperature gradient of molten pool was reduced, heat distribution became uniform, and keyhole area was enlarged. In addition, the flow velocity of molten pool was increased, the vorticity of molten pool was improved, and the flow region of liquid metal was enlarged. Experimental results showed that penetration of molten pool was deeper, the shape of welding pool tended to be symmetrical and the density of Al element distribution in welding pool was increased by magnetic field. Thus, heat and mass transfer in welding pool was promoted due to the application of magnetic field, the elements exchange and the convection of liquid metal were accelerated, and the distribution of Mg-Al compounds should be dispersed under the agitation of Lorentz force. It's predicted that the distribution of Mg-Al compounds in magnesium/aluminum laser welding would be positively affected by magnetic field, which was beneficial to control the weld quality. Hence, numerical results and experimental verification shared good consistency.

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