If perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs) are to be commercialized, they must achieve long-term stability, which is usually assessed with accelerated degradation tests. One of the persistent obstacles for PSCs has been successfully passing the damp-heat test (85°C and 85% relative humidity), which is the standard for verifying the stability of commercial photovoltaic (PV) modules. We fabricated damp heat–stable PSCs by tailoring the dimensional fragments of two-dimensional perovskite layers formed at room temperature with oleylammonium iodide molecules; these layers passivate the perovskite surface at the electron-selective contact. The resulting inverted PSCs deliver a 24.3% PCE and retain >95% of their initial value after >1000 hours at damp-heat test conditions, thereby meeting one of the critical industrial stability standards for PV modules.
Organic-inorganic halide perovskite-based thin film solar cells show excellent light-to-power conversion efficiency. The high performance for the devices requires the preparation of well-crystallized perovskite absorbers. In this paper, we used the postannealing process to treat the perovskite films under different solvent vapors and observed that the solvent vapors have a strong effect on the film growth. A model regarding the perovskite film growth was proposed as well. Intensive characterizations including scanning electron microscopy, electrochemical impedance spectroscopy, and admittance spectroscopy allowed us to attribute the improved performance to reduced recombination loss and defect density. Solar cell based on the DMSO-treated films delivered a power conversion efficiency of over 13% with negligible photocurrent hysteresis.
The performance of perovskite solar cells with inverted polarity (
p-i-n
) is still limited by recombination at their electron extraction interface, which also lowers the power conversion efficiency (PCE) of
p-i-n
perovskite-silicon tandem solar cells. A ~1 nm thick MgF
x
interlayer at the perovskite/C
60
interface through thermal evaporation favorably adjusts the surface energy of the perovskite layer, facilitating efficient electron extraction, and displaces C
60
from the perovskite surface to mitigate nonradiative recombination. These effects enable a champion
V
oc
of 1.92 volts, an improved fill factor of 80.7%, and an independently certified stabilized PCE of 29.3% for a ~1 cm
2
monolithic perovskite-silicon tandem solar cell. The tandem retained ~95% of its initial performance following damp-heat testing (85 Celsius at 85% relative humidity) for > 1000 hours.
A new amino-functionalized polymer, PN4N, was developed and applied as an efficient interlayer to improve the cathode interface of fullerene/perovskite (CH3NH3PbIxCl3−x) planar heterojunction solar cells.
The performance of a fl exible transparent conductive electrode with extremely smooth topography capable of withstanding thermal processing at 300 °C for at least 6 h with little change in sheet resistance and optical clarity is reported. In depth investigation is performed on atomic layer deposition (ALD) deposited ZnO on Ag nanowires (NWs) with regard to thermal and atmospheric corrosion stability. The ZnO coated nanowire networks are embedded within the surface of a polyimide matrix, and the <2 nm roughness freestanding electrode is used to fabricate a white polymer light emitting diode (PLED). PLEDs obtained using the ZnO-AgNW-polyimide substrate exhibit comparable performance to indium tin oxide (ITO)/glass based devices, verifying its efficacy for use in optoelectronic devices requiring high processing temperatures.
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