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The project studied the occurrence, fate, and seasonal variation of 14 antibiotics, from five wastewater treatment plants (WWTPs) in Shanghai. The results indicated that ofloxacin, sulfamethoxazole, and oxytetracycline were the predominant antibiotics, with maximum concentrations of 1208.20, 959.13, and 564.30 ng/L in influents, while 916.88, 106.60, and 337.81 ng/L in effluents, respectively. The level of antibiotics in WWTPs obviously varied with seasonal changes, and higher detectable frequencies and concentrations were found in winter. The daily mass loads per capita of amoxicillin, enrofloxacin, and oxytetracycline in the study were all higher than those in other regions/countries, such as Hong Kong, Australia, and Italy. The elimination of antibiotics through these WWTPs was incomplete, and a wide range of removal efficiencies during the different treatment process and seasons were observed (-500.56 to 100 % in winter and -124.24 to 94.21 % in summer). Sulfonamides were relatively easy to be removed in WWTPs and the ultraviolet (UV) process can effectively improve the removal efficiency. Risk assessment of antibiotics in effluents was estimated. Only AMOX's hazard quotient (HQ) was higher than 0.01. Even though the environmental risks in the study were estimated to be low, the potential negative effects on aquatic ecosystems should call our attention as continually discharge in the long term.

Antidepressants are gaining public attention because of increasing reports of their occurrence in environment and their potential impact on ecosystems and human health. Continuous input of pharmaceuticals into rivers, through psychiatric hospital or wastewater treatment plant (WWTPs) effluent, may cause adverse effects on the aquatic ecosystems of the receiving water bodies. This work investigates the occurrence and sources of 8 antidepressants in main stream and tributaries of Huangpu River in Shanghai. The detected concentrations of the selected antidepressants ranged from low nanogram per liter to 42.9 ng L (fluoxetine) in main stream and ranged from low nanogram per liter to 33.7 ng L (fluoxetine) in tributaries. To study the effect of hospital or wastewater treatment plants (WWTPs) on environment, the upstream and downstream samples were analyzed. Generally, antidepressants had greater concentrations in downstream than that in upstream of the WWTPs or hospitals. It is suggesting that WWTPs and hospitals may introduce pollution into water environment. A preliminary risk assessment was conducted: none of the eight target compounds yielded risk quotient (RQ) values more than 0.1, thus indicating that no adverse effect is expected in water environment. These results will provide background data for future antidepressants pollution control and management in Shanghai, China.

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The occurrence and fate of five endocrine disrupting chemicals (EDCs), including nonylphenol (NP), 4-tert-octylphenol (4-t-OP), 4-tert-butylphenol (4-t-BP), bisphenol A (BPA) and norethindrone (NET) was investigated in four wastewater treatment plants (WWTPs) and receiving river (Suzhou River and Yangtze River) of Shanghai. Selected EDCs in WWTPs influents ranged from 1.02 to 3560 ng L, which dominated by NP and BPA. Target compounds detected in effluents were from N.D. to 1136 ng L, with NP as most prevalent. The removal rates of target compounds varied from negative of NET to 99 % of BPA. Except of NET, efficiently removal rates (>70 %) were observed in WWTPs. Biological treatment was the major removal stage of selected EDCs in WWTPs. Furthermore, the selected EDCs were detected from N.D. to 424 ng L in receiving river. The correlation analysis suggested EDCs pollution in receiving river might be mainly contributed by WWTPs effluents. The risk quotient of NP (RQ > 1) was higher than any other pollutants, indicating its relatively higher potential risk for the aquatic organism. These results will provide significant background data to future EDCs pollution control and management in Shanghai, China.