The MQ silicone resin was synthesized by using chlorotrimethylsilane and tetraethyl orthosilicate and its structure was analyzed by means of Fourier transform infrared spectroscopy, 29Si-nuclear magnetic resonance and gel permeation chromatography. The silicone based pressure sensitive adhesive was obtained by condensation polymerization between the MQ resin and methyl silicone rubber terminated with hydroxyl group. The structure of the adhesive was characterized by FTIR, and its thermal properties were investigated via thermogravimetic analysis. The results show that the MQ resin successfully had a condensation polymerization reaction with the silicone rubber. The pressure sensitive adhesive had excellent tack, peel strength and high temperature resistance properties.
The water based acrylic pressure sensitive adhesive was synthesized by seeded pre-emulsion polymerization, the influence of the amount of seeded pre-emulsion, and tri-functional aziridine crosslinker on the properties of the adhesive were studied. It was found that with the increase of the amount of seeded pre-emulsion, latex particle size decreases, contrasted with the increase of the viscosity, surface tension and contact angle of the emulsion; The aging performance of the adhesive can be significantly improved with the increase of the content of the crosslinker; compared with high temperature, high humidity has a more worse negative effect on the aging performance of the adhesive.
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