Synthesis and Characterization of Water Based Acrylic Pressure Sensitive Adhesive of Surface Protection Tape

He, Min; Zhang, Qiu Yu; Guo, Ji Ying

doi:10.4028/www.scientific.net/amr.306-307.1785

Cited by 6 publications

(1 citation statement)

References 1 publication

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“…Polyacrylate latex is commonly used for preparing film-coated fertilizer granules and can be cross-linked via the side groups of its molecular chains. For instance, acrylic acid is initially added during the polymerization process, followed by the introduction of a cross-linker that can react with carboxyl groups, such as aziridine, , polycarbodiimide, epoxide, or metal ions . Functional monomers bearing specific reactive groups, such as ketocarbonyl-hydrazide or hydroxymethyl, can also be incorporated to facilitate cross-linking.…”

Section: Introductionmentioning

confidence: 99%

Enhancing Film Cross-Linking through VTES Copolymerization in Polymer Latex for Increasing Controlled-Release Performance of Film-Coated Fertilizer Granules

Xie,

Zhao,

Tan

et al. 2024

ACS Agric. Sci. Technol.

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To increase the controlled-release performance of film-coated fertilizer granules using polymer latex as a coating reagent, increasing the cross-linking density of the film during spray coating is crucial. In this study, vinyltriethoxysilane (VTES) was incorporated into styrene-acrylate copolymer latex, with film cross-linking achieved by the condensation of silanol groups derived from the hydrolysis of VTES. VTES-copolymerized latex-coated urea granules were prepared by spray coating in a fluidized bed. The film cross-linking density and controlled-release performance were significantly increased. The structural characteristics of the film cross-linked network were theoretically calculated and analyzed. The cross-linked network with high cross-linking density had a smaller size of mesh structure, significantly reducing the free volume of the film and increasing the diffusion resistance of nutrients. The urea diffusion coefficient across the planar film decreased from 2.74 × 10–15 to 0.125 × 10–15 m2/s when the VTES copolymerized ratio reached 10%. At a low coating amount of 4 wt %, the release period of the film-coated urea granules increased to 32 days, surpassing that of the reference sample by over 300%.

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