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[1] Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20-30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These serpentinites have U-shaped rare earth element (REE) patterns, resembling those of boninites. U, Th, and the high field strength elements (HFSE) are highly depleted and vary in concentration by up to 2 orders of magnitude. The low U contents and positive Eu anomalies indicate that fluids from the subducting Pacific slab were probably reducing in nature. On the basis of substantial enrichments of fluid-mobile elements in serpentinized peridotites, we calculated very large slab inventory depletions of B (79%), Cs (32%), Li (18%), As (17%), and Sb (12%). Such highly enriched serpentinized peridotites dragged down to depths of arc magma generation may represent an unexplored reservoir that could help balance the input-output deficit of these elements as observed by Plank and Langmuir (1993, 1998) and others. Surprisingly, many species thought to be mobile in fluids, such as U, Ba, Rb, and to a lesser extent Sr and Pb, are not enriched in the rocks relative to the depleted mantle peridotites, and we estimate that only 1-2% of these elements leave the subducting slabs at depths of 10 to 40 km. Enrichments of these elements in volcanic front and behind-the-front arc lavas point to changes in slab fluid composition at greater depths.

International Ocean Discovery Program (IODP) Expedition 352 recovered a high-fidelity record of volcanism related to subduction initiation in the Bonin fore-arc. Two sites (U1440 and U1441) located in deep water nearer to the trench recovered basalts and related rocks; two sites (U1439 and U1442) located in shallower water further from the trench recovered boninites and related rocks. Drilling in both areas ended in dolerites inferred to be sheeted intrusive rocks. The basalts apparently erupted immediately after subduction initiation and have compositions similar to those of the most depleted basalts generated by rapid sea-floor spreading at mid-ocean ridges, with little or no slab input. Subsequent melting to generate boninites involved more depleted mantle and hotter and deeper subducted components as subduction progressed and volcanism migrated away from the trench. This volcanic sequence is akin to that recorded by many ophiolites, supporting a direct link between subduction initiation, fore-arc spreading, and ophiolite genesis

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[1] Shallow slab devolatilization is not only witnessed through fluid expulsion at accretionary prisms, but is also evidenced by active serpentinite seamounts in the shallow fore-arc region of the Mariana convergent margin. Ocean Drilling Program (ODP) Leg 195 recovered serpentinized peridotites that present a unique opportunity to study the products of shallow level exchanges between the upper mantle and slab-derived fluids. Similar to samples recovered during ODP Leg 125, the protoliths of these fore-arc serpentinized peridotites are mantle harzburgites that have suffered large volume melt extraction (up to 25%) prior to interactions with fluids released from the downgoing Pacific Plate. Samples recovered from both ODP legs 125 and 195 show U-shaped rare earth element (REE) patterns and very low REE abundances (0.001-0.1 Â chondrites). Relative to global depleted mantle values these rocks typically have 1-2 orders of magnitude lower high field strength elements, REE, Th, and U contents. Interestingly, all fore-arc rocks thus far examined show extreme enrichments of fluid mobile elements (FME: B, As, Cs, Sb, Li). Because the elemental and B, Li, and Sr isotope systematics in these fore-arc serpentinites point to nonseawater-related processes, studies of elemental excesses and anomalous isotopic signatures allow assessment of how much of the subducted inventory is lost during the initial subduction process between 10 and 40 km. On the basis of similar but substantial enrichments of FME in the Mariana fore-arc samples recovered at ODP legs 125 and 195, we report large slab inventory depletions of B ($75%), Cs ($25%), As ($15%), Li ($15%), and Sb ($8%); surprisingly low (generally less than 2%) depletions of Rb, Ba, Pb, U, Sr; and no depletions in REE and the high field strength elements (HFSE). Such slab-metasomatized mantle wedge materials may be dragged to depths of arc magma generation, as proposed by Tatsumi (1986) and Straub and Layne (2002) and thus represent an unexplored class of mantle material, different in its origins, physical properties and geochemical fingerprint from mantle rocks traditionally used in modeling a wide range of subduction zone processes.Citation: Savov, I. P., J. G. Ryan, M. D 'Antonio, and P. Fryer (2007), Shallow slab fluid release across and along the Mariana arcbasin system: Insights from geochemistry of serpentinized peridotites from the Mariana fore arc,

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Subduction initiation is one of the least understood aspects of plate tectonics. In an effort to obtain the first in situ magmatic record of subduction initiation, the International Ocean Discovery Program Expedition 352 drilled at four sites in the inner trench wall of the Bonin Trench to recover 1.22 km of oceanic upper crust accreted within a few m.y. of subduction initiation. The two sites nearer to the trench (U1440 and U1441) yielded axial and off-axis fore-arc basalts (FAB), while those c. 15 km further from the trench (U1439 and U1442) yielded axial low-silica boninites and high-Mg andesites overlain by off-axis high-silica boninites. This study uses Hf-Nd-Sr-Pb isotope analyses from c. 50 stratigraphically representative core samples to trace the evolution of the mantle source during the brief period of FABthrough-boninite magmatism immediately following subduction initiation. Results show that: 1) the FAB have high εHf relative to εNd and were derived from variably depleted mantle of 'Indian' provenance with no detectable subduction input; 2) the axial boninites follow mixing trends between a residual FAB mantle source and a subduction component derived from shallow (amphibolite facies) melting of oceanic crust of 'Pacific' provenance; and 3) the off-axis boninites define mixing trends between a hybrid mantle wedge (residual mantle + slab melt) and an additional subduction component with lower εNd and higher 207 Pb/ 204 Pb that requires a significant contribution from pelagic sediment. This incoming of pelagic sediments may signify a change from an accretionary to non-accretionary margin as subduction evolves. The results thus indicate a rapidly evolving system in terms of geodynamics, magma genesis and crustal accretion immediately following subduction initiation.

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