J. J. Mayerle scite author profile

A phase transition starting at 84 K and indicated by a marked color change of the sample has been found in the organic insulator tetrathiafulvalene-chloranil. Optical, infrared, and Raman measurements indicate that this is a reversible transition from a nominally neutral (N) solid to a nominally ionic (D salt. Surprisingly, the N-I transition is not first order, but occurs over a broad temperature region (~ 30 K), in which there is a coexistence of N and I molecules.

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Synthetic analogs of the active sites of iron-sulfur proteins. XI. Synthesis and properties of complexes containing the iron sulfide (Fe2S2) core and the structures of bis[o-xylyl-.alpha.,.alpha.'-dithiolato-.mu.-sulfido-ferrate(III)] and bis[p-tolylthiolato-.mu.-sulfido-ferrate(III)] dianions

Mayerle

et al. 1975

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Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters [tetra-.mu.-sulfido-tetrakis(alkyl or aryl thiolato)tetraferrate](2-)

Holm¹,

Phillips²,

Averill³

et al. 1974

J. Am. Chem. Soc.

113

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Mixed-stack complexes of tetrathiafulvalene. The structures of the charge-transfer complexes of TTF with chloranil and fluoranil

Mayerle¹,

Torrance²,

Crowley³

1979

Acta Crystallogr Sect B

130

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14-Coordinate uranium(IV). Structure of uranium borohydride by single-crystal neutron diffraction

Bernstein¹,

Hamilton²,

Keiderling³

et al. 1972

Inorg. Chem.

109

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Structural characterization of the neutral-ionic phase transition in tetrathiafulvalene-chloranil: evidence for C-H.cntdot..cntdot..cntdot.O hydrogen bonding

Batail¹,

LaPlaca²,

Mayerle³

et al. 1981

J. Am. Chem. Soc.

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Structural determinations of four mono- and binuclear tertiary phosphine and arsine complexes of copper(I) chloride

Gill¹,

Mayerle²,

Welcker³

et al. 1976

Inorg. Chem.

147

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J. J. Mayerle

Discovery of a Neutral-to-Ionic Phase Transition in Organic Materials

Anomalous Nature of Neutral-to-Ionic Phase Transition in Tetrathiafulvalene-Chloranil

Synthetic analogs of the active sites of iron-sulfur proteins. XI. Synthesis and properties of complexes containing the iron sulfide (Fe2S2) core and the structures of bis[o-xylyl-.alpha.,.alpha.'-dithiolato-.mu.-sulfido-ferrate(III)] and bis[p-tolylthiolato-.mu.-sulfido-ferrate(III)] dianions

Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters [tetra-.mu.-sulfido-tetrakis(alkyl or aryl thiolato)tetraferrate](2-)

Mixed-stack complexes of tetrathiafulvalene. The structures of the charge-transfer complexes of TTF with chloranil and fluoranil

14-Coordinate uranium(IV). Structure of uranium borohydride by single-crystal neutron diffraction

Structural characterization of the neutral-ionic phase transition in tetrathiafulvalene-chloranil: evidence for C-H.cntdot..cntdot..cntdot.O hydrogen bonding

Structural determinations of four mono- and binuclear tertiary phosphine and arsine complexes of copper(I) chloride

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