We study the quantization of many-body systems in three dimensions in rotating coordinate frames using a gauge invariant formulation of the dynamics. We consider reference frames defined by linear gauge conditions, and discuss their Gribov ambiguities and commutator algebra. We construct the momentum operators, inner-product and Hamiltonian in those gauges, for systems with and without translation invariance. The analogy with the quantization of non-Abelian Yang-Mills theories in noncovariant gauges is emphasized. Our results are applied to quasi-rigid systems in the Eckart frame.
The thermal characterization of composites made up by magnetically aligned carbonyl iron micro-sized particles embedded in a polyester resin matrix is performed using photothermal radiometry technique. The measured experimental data show that the thermal conductivity and thermal diffusivity of the composite, in the direction of the applied magnetic field, increase with the concentration of the particles and are enhanced with respect to their corresponding values for a random distribution of the particles. This thermal enhancement has a maximum at a concentration of particles of 10% and is very low at small and high iron volume fractions, such that for particles concentrations of about 40%, the composite thermal conductivity reduces to its values for random particles. This behavior indicates that for high volume fractions, the effect of the microparticles concentration plays a dominant role over the effect of their alignment. It is shown that the thermal conductivity of the composite can be modeled in terms of the Nielsen model, under an appropriate parameterization of the form factor of the particles. The results of this work could be highly useful for improving the thermal performance of mechanical and electronic devices involving composite materials.
ZnO nanoparticles (NPs) were extracted from a commercial paste in both colloidal and precipitate forms. The Zetasizer analysis performed on the colloid showed ZnO NPs ranging from ∼30 nm to ∼100 nm. Thin films of ZnO were deposited on glass substrates by spin-coating technique from a mixture of the extracted colloid and precipitate. The scanning electron microscope (SEM) images showed uniformly arranged, mesoporous, and nanostructured ZnO particles of different shapes, with an estimated film thickness of 0.67 μm. Analysis by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction analysis (XRD) confirmed the presence of ZnO in the films, with no impurities or remnants of other materials. The XRD analysis showed a polycrystalline nature of the films and identified a pure phase formation of the hexagonal wurtzite structure. The average crystallite size calculated from the diffraction peaks is ∼43.25 nm. The calculated crystal tensile strain is 1.954 × 10−3, which increases the crystal volume by 0.728% compared with the crystal volume of standard ZnO. The calculated crystal parameters are a = b = 3.258 Å and c = 5.217 Å. The calculated dislocation density (d) and bond length Zn–O (L) are 5.35 × 10−4 nm−2 and 2.695 Å, respectively. Ultraviolet-visible absorption spectra showed an optical band gap of ∼3.80 eV.
ZnO thin films were deposited on ITO/glass substrates by pulsed laser deposition (PLD) using two different kinds of targets. One of the targets was made of pure ZnO powder and the other one consisted of a mixture of ZnO powder with cyanoacrylate glue. The structural and morphological properties of the films obtained using both targets were compared, in order to determine which one produces samples with properties more suitable for their use as buffer and antireflective layer in CdTe-based solar cells, also different heterostructures were deposited to study the optical properties of the obtained thin films and their utility in the applications mentioned before. The films deposited with the mixture powder target were polycrystalline with preferential orientations in the planes (100) and (101) with a high transmittance in the range of 70-90% in the 540-850 nm wavelength region and showed a high resistivity of ∼1.30×10 2 cm −1 , such properties are considered to be appropriate for thin films that are wanted to be used as a buffer and antireflective layer in CdTe solar cells.
As the use of photovoltaic installations becomes extensive, it is necessary to look for recycling processes that mitigate the environmental impact of damaged or end-of-life photovoltaic panels. There is no single path for recycling silicon panels, some works focus on recovering the reusable silicon wafers, others recover the silicon and metals contained in the panel. In the last few years, silicon solar cells are thinner, and it becomes more difficult to separate them from the glass, so the trend is towards the recovery of silicon. In this paper, we investigate the experimental conditions to delaminate and recovery silicon in the recycling process, using a combination of mechanical, thermal, and chemical methods. The conditions of thermal treatment to remove the ethylene-vinyl acetate (EVA) layer were optimized to 30 min at 650 °C in the furnace. To separate silicon and metals, the composition of HF/HNO3 solution and the immersion time were adjusted considering environmental aspects and cost. Under the selected conditions, panels from different manufacturers were tested, obtaining similar yields of recovered silicon but differences in the metal concentrations.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.