In the R 3 Ga 5 SiO 14 compounds, the network R of rare earth cations form well separated planes of corner sharing triangles topologically equivalent to a kagomé lattice. Powder samples and single crystals with R = Nd and Pr were prepared and magnetostatic measurements were performed under magnetic field up to 10 T in the temperature range from 1.6 K to 400 K. Analysis of the magnetic susceptibility at the high temperatures where only the quadrupolar term of the crystal electric field prevails, suggests that the Nd and Pr magnetic moments can be modeled as coplanar elliptic rotators perpendicular to the three fold axis of the crystal structure that interact antiferromagnetically. Nonetheless, a disordered phase that can be ascribed to geometric frustration persists down to the lowest temperature which is about 25 times smaller than the energy scale for the exchange interactions.
Hexagonal YMnO 3 and HoMnO 3 as well as (YMnO 3 /HoMnO 3 ) 15 superlattices were grown on (111) ZrO 2 (Y 2 O 3 ) and (111) Pt/TiO 2 /SiO 2 /p-type (100)Si substrates. Epitaxial stabilization was used on the same substrates to grow DyMnO 3 or TbMnO 3 (which normally crystallize in an orthorhombic, perovskite-type, structure). All heterostructures were obtained oriented, with the c-axis of the hexagonal cell perpendicular to the substrate plane. This orientation is desired since it is the direction of the ferroelectric polarization in hexagonal manganites. The strain state of the films grown on conductive Pt electrodes, tracked by the evolution of the c parameter as a function of film thickness, was found to be completely different than the one obtained on YSZ. Such a study is important for future strain engineering in multilayers. Highresolution transmission electron microscopy on superlattices grown on (111)Pt indicates a high crystalline quality along the c-axis and sharp interfaces.
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