Ti and Ti-TiB composite materials were produced by selective laser melting (SLM). Ti showed an α΄ microstructure, whereas the Ti-TiB composite revealed a distribution of needle-like TiB particles across an α-Ti matrix. Hardness (H) and reduced elastic modulus (Er) were investigated by nanoindentation using loads of 2, 5 and 10 mN. The results showed higher H and Er values for the Ti-TiB than Ti due to the hardening and stiffening effects of the TiB reinforcements. On increasing the nanoindentation load, H and Er were decreased. Comparison of the nanoindentation results with those derived from conventional hardness and compression tests indicated that 5 mN is the most suitable nanoindentation load to assess the elastic modulus and hardness properties. The wear resistance of the samples was related to their corresponding H/Er and H3/Er2 ratios obtained by nanoindentation. These investigations showed that there is a high degree of consistency between the characterization using nanoindentation and the wear evaluation from conventional wear tests
produced by dealloying have outstanding physical properties due to their unique structure with open porous networks, [3][4][5] the undesirable coarsening phenomenon leads to degradation of physical properties over time, even at room temperature. [6][7][8] The originally proposed idea behind high-entropy alloy (HEA) with multiprinciple elements is maximizing the configuration entropy to stabilize a solid-solution alloy without undesired ordered intermetallics. [9][10][11] Many studies have suggested that HEAs uniquely possesses combined desirable properties such as a high strength and ductility paired with high fracture toughness, [12][13][14] fatigue resistance, [15] and creep resistance. [16] HEAs also show promising properties in harsh environments resisting corrosion, [17][18][19] and irradiation [20] attacks. Atomic size differences between constituting elements in HEA increase the activation energy for grain growth, and sluggish diffusion kinetics has considered as the main reason for the exceptional high strength and structural stability of HEAs at high temperatures. [21,22] The rationale behind it, the multiprinciple elements cause larger fluctuations in lattice potential energy (LPE), providing many low-LPE sites that hinder atomic diffusion. [23] Grain growth and ligament coarsening rely on the same physical background of surface diffusion. In that context, the high-entropy design in nanoporous materials has a potential for achieving an exceptional stability against the coarsening.Controlling the feature sizes of 3D bicontinuous nanoporous (3DNP) materials is essential for their advanced applications in catalysis, sensing, energy systems, etc., requiring high specific surface area. However, the intrinsic coarsening of nanoporous materials naturally reduces their surface energy leading to the deterioration of physical properties over time, even at ambient temperatures. A novel 3DNP material beating the universal relationship of thermal coarsening is reported via high-entropy alloy (HEA) design. In newly developed TiVNbMoTa 3DNP HEAs, the nanoporous structure is constructed by very fine nanoscale ligaments of a solid-solution phase due to enhanced phase stability by maximizing the configuration entropy and suppressed surface diffusion. The smallest size of 3DNP HEA synthesized at 873 K is about 10 nm, which is one order of magnitude smaller than that of conventional porous materials. More importantly, the yield strength of ligament in 3DNP HEA approaches its theoretical strength of G/2π of the corresponding HEA alloy even after thermal exposure. This finding signifies the key benefit of high-entropy design in nanoporous materials-exceptional stability of size-related physical properties. This high-entropy strategy should thus open new opportunities for developing ultrastable nanomaterials against its environment.The ORCID identification number(s) for the author(s) of this article can be found under https://doi.
The long-term performance of orthopedic implants depends crucially on a close match between the mechanical behavior of bone and of the implant material. Yet, the present man-made materials with the required biocompatibility and strength are substantially stiffer than bone. This mismatch results in stress shielding, which can lead to the loss of bone mass and may even lead to a revision surgery. Here we report a new materials design strategy towards metal-polymer composites that are based on constituents with established biocompatibility and that can be matched to bone. Ti-based nanoporous alloys, prepared by liquid-metal dealloying, are infiltrated with epoxy to form interpenetrating-phase nanocomposites. At up to 260 MPa, their yield strength is technologically interesting for a deformable light-weight material. More importantly, Young’s modulus can be adjusted between 4.4 and 24 GPa, which affords matching to bone. As another parallel to bone, the strength of the composite materials is strain-rate dependent. These findings suggest that the novel composite materials may provide the basis for promising future implant materials.
Metallic glasses (MGs) inherit their amorphous structure from the liquid state, which predetermines their ability to withstand high loads approaching the theoretical limit. However, the absence of slip systems makes them very sensitive to the type of loading and extremely brittle in tension. The latter can be improved by precipitation of ductile crystals, which suppress a catastrophic propagation of shear bands in a glassy matrix. Here we report a novel approach to obtain MG-matrix composites with tensile ductility by flash Joule heating applied to Cu47.5Zr47.5Al5 (at.%) metallic glass. This homogeneous, volumetric and controllable rapid heat treatment allows achieving uniformly distributed metastable B2 CuZr crystals in the glassy matrix. It results in a significant tensile strain of 6.8±0.5%. Moreover, optimized adjustment of the heat-treatment conditions enables tuning of microstructure to achieve desired mechanical properties.
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