Through understanding that the fluid in the vortex fluidic device (VFD) housing an inclined rapidly rotating tube exhibits resonance behaviours from the confining boundaries of the glass surface and the...
Graphene oxide scrolls (GOS) are fabricated in high yield from a colloidal suspension of graphene oxide (GO) sheets under shear stress in a vortex fluidic device (VFD) while irradiated with a pulsed laser operating at 1064 nm and 250 mJ. This is in the absence of any other reagents with the structure of the GOS established using powder X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry, X-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy, atomic force microscopy and scanning electron microscopy.
Micromixing of an o-xylene solution of C60 with N-N-dimethylformamide (DMF) at room temperature under continuous flow in a vortex fluidic device (VFD) results in the formation of symmetrical right cones in high yield with diameters 0.5 to 2.5 μm, pitch angle 25° to 55° and wall thickness 120 to 310 nm. Their formation is in the absence of surfactants and any other reagents, and is scalable. The cones are formed at specific operating parameters of the VFD, including rotational speed, flow rate and concentration, and varying these results in other structures such as grooved fractals. Other aromatic solvents in place of o-xylene results in the formation of rods, spicules and prisms, respectively for m-xylene, p-xylene and mesitylene.
Applications of multi-walled carbon nanotubes (MWCNTs) benefit from the availability of specific lengths of the material while keeping the outer walls pristine, for example, for applications requiring vertically aligned tubes.
<b>Induced mechanical energy in a thin film of
liquid in an inclined rapidly rotating tube in the vortex fluidic device (VFD)
can be harnessed for generating non-equilibrium conditions, which are optimal
at 45<sup>o</sup> tilt angle, but the nature of the fluid flow is not understood.
Through understanding that the fluid exhibits resonance behaviours from the
confining boundaries of the glass surface and the meniscus that determines the
liquid film thickness, we have established specific topological mass transport
regimes. These topologies have been established through materials processing,
as circular flow normal to the surface of the tube, double-helical flow across
the thin film, and spicular flow, a transitional region where both effects
contribute. This includes new phenomenological shear stressed crystallization
and molecular drilling. The manifestation of these patterns has been observed
by monitoring mixing times, temperature profiles, and film thickness against
rotational speed of liquids in the tube. The grand sum of the different
behavioural regimes is a general fluid flow model that accounts for all
processing in the VFD at an optimal tilt angle of 45<sup>o</sup>, and provides
a new concept in the fabrication of novel nanomaterials and controlling the
organisation of matter.</b>
<b>Induced mechanical energy in a thin film of
liquid in an inclined rapidly rotating tube in the vortex fluidic device (VFD)
can be harnessed for generating non-equilibrium conditions, which are optimal
at 45<sup>o</sup> tilt angle, but the nature of the fluid flow is not understood.
Through understanding that the fluid exhibits resonance behaviours from the
confining boundaries of the glass surface and the meniscus that determines the
liquid film thickness, we have established specific topological mass transport
regimes. These topologies have been established through materials processing,
as circular flow normal to the surface of the tube, double-helical flow across
the thin film, and spicular flow, a transitional region where both effects
contribute. This includes new phenomenological shear stressed crystallization
and molecular drilling. The manifestation of these patterns has been observed
by monitoring mixing times, temperature profiles, and film thickness against
rotational speed of liquids in the tube. The grand sum of the different
behavioural regimes is a general fluid flow model that accounts for all
processing in the VFD at an optimal tilt angle of 45<sup>o</sup>, and provides
a new concept in the fabrication of novel nanomaterials and controlling the
organisation of matter.</b>
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