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The structural phase transitions in [N(CH 3 ) 4 ]CdCl 3 were investigated by means of adiabatic calorimetry and thermal expansion measurements. Two phase transitions have been studied on cooling and on heating at about 104 K and 118 K. The shapes of the observed specific heat anomalies, as well as the existence of thermal hysteresis, confirm the first-order character previously assigned to these phase transitions. From the experimental data and the harmonic specific heat obtained from the known frequencies of the vibrational modes, a calculation of the Grüneisen parameter as a function of the temperature is also given. Finally, the suitability of different Landau potentials for the two phase transitions is briefly discussed.

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A calorimetric study of urea/n-nonadecane, CO(NH(2))(2)/C(19)H(40), and the deuterated derivatives, CO(ND(2))(2)/C(19)D(40) and CO(NH(2))(2)/C(19)D(40), around the structural phase transition temperature is presented. For this purpose differential scanning (DSC), temperature-modulated (AC) and adiabatic calorimetry have been used and the obtained results are compared. Leaving apart the noticeable peak associated with the main phase transition at 158.5, 149.4 and 154 K respectively, small anomalies of the specific heat are found at lower temperatures and their corresponding entropic and enthalpic changes are reported. Heating and cooling experiments show the influence of the temperature rate and the thermal history on the detailed profile of the specific heat traces. The presence of thermal hysteresis and latent heat as a way to characterize the order of the phase transitions is discussed. Finally, a tentative approach to the urea and the alkyl chain contributions to the specific heat and their influence on the phase transition mechanisms is presented.

Shape memory alloys are one of the most important families of functional materials due to superelasticity and shape memory properties. In particular Cu‐Al‐Ni alloys exhibit these properties at nanoscale, becoming potentially useful to design new smart MEMS. In this work, an anomalous behavior observed during nano‐compression superelastic tests on Cu‐Al‐Ni shape memory alloy micro pillars is reported. The study is approached by nano‐compression tests on micro and nano pillars milled by focused ion beam. The anomalous behavior on the superelastic effect is manifested by a sudden stabilization of the stress‐induced martensite, which does not undergo the reverse transformation. A transition, from superelastic to pseudoelastic‐twinning behavior, takes place during the nano‐compression tests, and is evaluated through the load‐depth curves and quantified by the mechanical damping coefficient η, which undergoes a sharp change from ultra‐high damping, η > 0.1, down to η ≈ 0.01. The stabilization of the martensite occurs under two different experimental conditions, along cycling and by applying a very high stress during superelastic tests. In both cases, a further recovery of the initial superelastic behavior is registered. The mechanisms responsible for the observed stabilization and recovery are discussed, together with the implications and further requirements for technological applications in MEMS.