Studies of the nonlinear optical phenomena that describe the light‐matter interactions in 2D crystalline materials have promoted a diverse range of photonic applications. MXene, as a recently developed new 2D material, has attracted considerable attention because of its graphene‐like but highly tunable and tailorable electronic/optical properties. In this study, we systematically characterize the nonlinear optical response of MXene Ti3C2Tx nanosheets over the spectral range of 800 nm to 1800 nm. A large effective nonlinear absorption coefficient (βeff∼‐10−21 m2/V2) due to saturable absorption is observed for all of the testing wavelengths. The contribution of saturable absorption is two orders of magnitude higher than other lossy nonlinear absorption processes, and the amplitude of βeff strongly depends on the light bleaching level. A negative nonlinear refractive index (n2∼‐10−20 m2/W) with value comparable to that of the intensively studied graphene was demonstrated for the first time. These results demonstrate the efficient broadband light signal manipulating capabilities of Ti3C2Tx, which is only one member of the large MXene family. The capability of an efficient broadband optical switch is strongly confirmed using Ti3C2Tx as saturable absorbers for mode‐locking operation at 1066 nm and 1555 nm, respectively. A highly stable femtosecond laser with pulse duration as short as 159 fs in the telecommunication window is readily obtained. Considering the diversity of the MXene family, this study may open a new avenue to advanced photonic
devices.
Recent advances in emerging Janus two-dimensional materials including fundamental physics, unique properties and potential device applications are reviewed.
Broadband Nonlinear Photonics
MXene has attracted considerable attention as a recently developed 2D material due to its graphene‐like but highly tunable and tailorable electronic/optical properties. In article number 1700229, Qiao Wen, Han Zhang, and co‐workers investigate broadband nonlinear optical responses in few‐layer MXene Ti3C2Tx with values comparable to graphene. Furthermore, the authors demonstrate a compact femtosecond fiber laser in the telecommunication window using Ti3C2Tx as a fast saturable absorber.
Silicon photonics is being extended from the near-infrared window of 1.3-1.5 µm for optical fiber communications to the mid-infrared (mid-IR) wavelength-band of 2 µm or longer for satisfying the increasing demands in many applications. Mid-IR waveguide photodetectors on silicon have attracted intensive attention as one of the indispensable elements for various photonic systems. However, when combining traditional semiconductor materials with silicon, there are some challenges due to lattice mismatch and thermal expansion mismatch. As an alternative, two-dimensional (2D) materials provide a new and promising option for enabling active photonic devices on silicon. Here black-phosphorus (BP) thin films with optimized medium thicknesses (40 nm) are introduced as the active material for light absorption and silicon/BP hybrid ridge waveguide photodetectors at 2 µm are demonstrated with a high responsivity of 306.7 mA W −1 at a low bias voltage of 0.4 V. The 3 dB-bandwidth is up to 1.33 GHz and an experiment of a 4.0 Gbit s −1 data receiving is also demonstrated.
Low-symmetry layered materials such as black phosphorus (BP) have been revived recently due to their high intrinsic mobility and in-plane anisotropic properties, which can be used in anisotropic electronic and optoelectronic devices.
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