Recent advances in emerging Janus two-dimensional materials including fundamental physics, unique properties and potential device applications are reviewed.

The emerging monoelemental 2D materials named as Xenes including borophene, silicene, germanene, stanene, phosphorene, arsenene, antimonene, bisthumene, selenene, and tellurene, have attracted rising attention experimentally and theoretically. Because of their excellent and versatile physical, chemical, electrical, and optical advantages, Xenes have been shown or have been predicted to have excellent performance in nanotechnology applications, addressing challenges and advances in electronics, energy, healthcare, and environment. In this review, the basic fundamentals in the classification of the periodic table group and the synthesis methods for the emerging materials are summarized. Then, the hybridization, doping and functionalization of 2D Xenes, and their corresponding applications are presented. Furthermore, a summary of research progress on 2D Xenes and the challenges and perspectives for their further development are discussed.