Highly flexible transparent capacitive sensors have been demonstrated for the detection of deformation and pressure. The elastomeric sensors employ a pair of compliant electrodes comprising silver nanowire networks embedded in the surface layer of polyurethane matrix, and a highly compliant dielectric spacer sandwiched between the electrodes. The capacitance of the sensor sheets increases linearly with strains up to 60% during uniaxial stretching, and linearly with externally applied transverse pressure from 1 MPa down to 1 kPa. Stretchable sensor arrays consisting of 10 × 10 pixels have also been fabricated by patterning the composite electrodes into X-Y addressable passive matrix.
Recent technological advances have made a myriad of soft and flexible electronic devices possible. The essential materials behind many of these devices and systems are electrical conductors that are compliant and retain their conductivity at high strain deformation. These so-called "compliant conductors" are the class of materials that enable stretchable and flexible electrodes, interconnects, and other components utilized in soft electronics. Creating conductors with high compliance, conductivity, and transparency is not a trivial matter, since these properties are often mutually exclusive. Furthermore, engineering reliable compliant conductors with a desired set of properties that remain fairly unchanged over long service lifetimes is an additional criterion that merits careful attention. These challenges have been addressed through at least two primary approaches. The first has been to create conducting composites that are intrinsically stretchable, typically by filling elastomers with conductive particles, or by depositing conductive particles on or just beneath the surface of elastomers. The second strategy has been to build conducting structures capable of reversible bending or stretching. In this review, the key research efforts toward the development of compliant conductors, including transparent conductors, are surveyed for application in flexible and highly stretchable electronic and electromechanical devices.
A new compliant electrode-based on silver nanowire-polymer composite has been developed. The composite electrode has low sheet resistance (as low as 10 Ω/sq), remains conductive (10(2) -10(3) Ω/sq) at strains as high as 140%, and can support Joule heating. The combination of the composite and a bistable electroactive polymer produces electrically-induced, large-strain actuation and relaxation, reversibly without the need of mechanical programming.
Stretchable transparent composites have been synthesized consisting of a silver nanowire (AgNW) network embedded in the surface layer of a crosslinked poly(acrylate) matrix. The interpenetrating networks of AgNWs and the crosslinked polymer matrix lead to high surface conductivity, high transparency, and rubbery elasticity. The presence of carboxylic acid groups on the polymer chains enhances the bonding between AgNWs and the polymer matrix, and further increases the stretchability of the composites. The sheet resistance of the composite electrode increases by only 2.3 times at 50% strain. Repeated stretching to 50% strain and relaxation only causes a small increase of the sheet resistance after 600 cycles. The morphology of the composites during reversible stretching and relaxation has been investigated to expound the conductivity changes.
The novel conductive polyaniline/bacterial cellulose (PANI/BC) nanocomposite membranes have been synthesized in situ by oxidative polymerization of aniline with ammonium persulfate as an oxidant and BC as a template. The resulting PANI-coated BC nanofibrils formed a uniform and flexible membrane. It was found that the PANI nanoparticles deposited on the surface of BC connected to form a continuous nanosheath by taking along the BC template, which greatly increases the thermal stability of BC. The content of PANI and the electrical conductivity of composites increased with increasing reaction time from 30 to 90 min, while the conductivity decreased because of the aggregation of PANI particles by further prolonging the reaction time. In addition, the acids remarkably improve the accessibility and reactivity of the hydroxyl groups of BC. The results indicate that the composites exhibit excellent electrical conductivity (the highest value was 5.0 × 10(-2) S/cm) and good mechanical properties (Young's modulus was 5.6 GPa and tensile strength was 95.7 MPa). Moreover, the electrical conductivity of the membrane is sensitive to the strain. This work provides a straightforward method to prepare flexible films with high conductivity and good mechanical properties, which could be applied in sensors, flexible electrodes, and flexible displays. It also opens a new field of potential applications of BC materials.
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