With the arising of global climate change and resource shortage, in recent years, increased attention has been paid to environmentally friendly materials. Trees are sustainable and renewable materials, which give us shelter and oxygen and remove carbon dioxide from the atmosphere. Trees are a primary resource that human society depends upon every day, for example, homes, heating, furniture, and aircraft. Wood from trees gives us paper, cardboard, and medical supplies, thus impacting our homes, school, work, and play. All of the above-mentioned applications have been well developed over the past thousands of years. However, trees and wood have much more to offer us as advanced materials, impacting emerging high-tech fields, such as bioengineering, flexible electronics, and clean energy. Wood naturally has a hierarchical structure, composed of well-oriented microfibers and tracheids for water, ion, and oxygen transportation during metabolism. At higher magnification, the walls of fiber cells have an interesting morphology-a distinctly mesoporous structure. Moreover, the walls of fiber cells are composed of thousands of fibers (or macrofibrils) oriented in a similar angle. Nanofibrils and nanocrystals can be further liberated from macrofibrils by mechanical, chemical, and enzymatic methods. The obtained nanocellulose has unique optical, mechanical, and barrier properties and is an excellent candidate for chemical modification and reconfiguration. Wood is naturally a composite material, comprised of cellulose, hemicellulose, and lignin. Wood is sustainable, earth abundant, strong, biodegradable, biocompatible, and chemically accessible for modification; more importantly, multiscale natural fibers from wood have unique optical properties applicable to different kinds of optoelectronics and photonic devices. Today, the materials derived from wood are ready to be explored for applications in new technology areas, such as electronics, biomedical devices, and energy. The goal of this study is to review the fundamental structures and chemistries of wood and wood-derived materials, which are essential for a wide range of existing and new enabling technologies. The scope of the review covers multiscale materials and assemblies of cellulose, hemicellulose, and lignin as well as other biomaterials derived from wood, in regard to their major emerging applications. Structure-properties-application relationships will be investigated in detail. Understanding the fundamental properties of these structures is crucial for designing and manufacturing products for emerging applications. Today, a more holistic understanding of the interplay between the structure, chemistry, and performance of wood and wood-derived materials is advancing historical applications of these materials. This new level of understanding also enables a myriad of new and exciting applications, which motivate this review. There are excellent reviews already on the classical topic of woody materials, and some recent reviews also cover new understanding of these mate...
Metallic-phase MoS2 (M-MoS2) is metastable and does not exist in nature. Pure and stable M-MoS2 has not been previously prepared by chemical synthesis, to the best of our knowledge. Here we report a hydrothermal process for synthesizing stable two-dimensional M-MoS2 nanosheets in water. The metal–metal Raman stretching mode at 146 cm−1 in the M-MoS2 structure, as predicted by theoretical calculations, is experimentally observed. The stability of the M-MoS2 is associated with the adsorption of a monolayer of water molecules on both sides of the nanosheets, which reduce restacking and prevent aggregation in water. The obtained M-MoS2 exhibits excellent stability in water and superior activity for the hydrogen evolution reaction, with a current density of 10 mA cm−2 at a low potential of −175 mV and a Tafel slope of 41 mV per decade.
The intermittent nature of renewable energy sources, such as solar and wind, calls for sustainable electrical energy storage (EES) technologies for stationary applications. Li will be simply too rare for Li-ion batteries (LIBs) to be used for large-scale storage purposes. In contrast, Na-ion batteries (NIBs) are highly promising to meet the demand of grid-level storage because Na is truly earth abundant and ubiquitous around the globe. Furthermore, NIBs share a similar rocking-chair operation mechanism with LIBs, which potentially provides high reversibility and long cycling life. It would be most efficient to transfer knowledge learned on LIBs during the last three decades to the development of NIBs. Following this logic, rapid progress has been made in NIB cathode materials, where layered metal oxides and polyanionic compounds exhibit encouraging results. On the anode side, pure graphite as the standard anode for LIBs can only form NaC64 in NIBs if solvent co-intercalation does not occur due to the unfavorable thermodynamics. In fact, it was the utilization of a carbon anode in LIBs that enabled the commercial successes. Anodes of metal-ion batteries determine key characteristics, such as safety and cycling life; thus, it is indispensable to identify suitable anode materials for NIBs. In this Account, we review recent development on anode materials for NIBs. Due to the limited space, we will mainly discuss carbon-based and alloy-based anodes and highlight progress made in our groups in this field. We first present what is known about the failure mechanism of graphite anode in NIBs. We then go on to discuss studies on hard carbon anodes, alloy-type anodes, and organic anodes. Especially, the multiple functions of natural cellulose that is used as a low-cost carbon precursor for mass production and as a soft substrate for tin anodes are highlighted. The strategies of minimizing the surface area of carbon anodes for improving the first-cycle Coulombic efficiency are also outlined, where graphene oxide was employed as dehydration agent and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was used to unzip wood fiber. Furthermore, surface modification by atomic layer deposition technology is introduced, where we discover that a thin layer of Al2O3 can function to encapsulate Sn nanoparticles, leading to a much enhanced cycling performance. We also highlight recent work about the phosphorene/graphene anode, which outperformed other anodes in terms of capacity. The aromatic organic anode is also studied as anode with very high initial sodiation capacity. Furthermore, electrochemical intercalation of Na ions into reduced graphene oxide is applied for fabricating transparent conductors, demonstrating the great feasibility of Na ion intercalation for optical applications.
Solar cell substrates require high optical transparency but also prefer high optical haze to increase the light scattering and consequently the absorption in the active materials. Unfortunately, there is a trade-off between these optical properties, which is exemplified by common transparent paper substrates exhibiting a transparency of about 90% yet a low optical haze (<20%). In this work, we introduce a novel transparent paper made of wood fibers that displays both ultrahigh optical transparency (∼ 96%) and ultrahigh haze (∼ 60%), thus delivering an optimal substrate design for solar cell devices. Compared to previously demonstrated nanopaper composed of wood-based cellulose nanofibers, our novel transparent paper has better dual performance in transmittance and haze but also is fabricated at a much lower cost. This high-performance, low-cost transparent paper is a potentially revolutionary material that may influence a new generation of environmentally friendly printed electronics.
Sodium (Na)-ion batteries offer an attractive option for low cost grid scale storage due to the abundance of Na. Tin (Sn) is touted as a high capacity anode for Na-ion batteries with a high theoretical capacity of 847 mAh/g, but it has several limitations such as large volume expansion with cycling, slow kinetics, and unstable solid electrolyte interphase (SEI) formation. In this article, we demonstrate that an anode consisting of a Sn thin film deposited on a hierarchical wood fiber substrate simultaneously addresses all the challenges associated with Sn anodes. The soft nature of wood fibers effectively releases the mechanical stresses associated with the sodiation process, and the mesoporous structure functions as an electrolyte reservoir that allows for ion transport through the outer and inner surface of the fiber. These properties are confirmed experimentally and computationally. A stable cycling performance of 400 cycles with an initial capacity of 339 mAh/g is demonstrated; a significant improvement over other reported Sn nanostructures. The soft and mesoporous wood fiber substrate can be utilized as a new platform for low cost Na-ion batteries.
Due to their high ionic conductivity and adeciduate mechanical features for lamination, sulfide composites have received increasing attention as solid electrolyte in all-solid-state batteries. Their smaller electronegativity and binding energy to Li ions and bigger atomic radius provide high ionic conductivity and make them attractive for practical applications. In recent years, noticeable efforts have been made to develop high-performance sulfide solid-state electrolytes. However, sulfide solid-state electrolytes still face numerous challenges including: 1) the need for a higher stability voltage window, 2) a better electrode-electrolyte interface and air stability, and 3) a cost-effective approach for large-scale manufacturing. Herein, a comprehensive update on the properties (structural and chemical), synthesis of sulfide solid-state electrolytes, and the development of sulfide-based all-solid-state batteries is provided, including electrochemical and chemical stability, interface stabilization, and their applications in high performance and safe energy storage.
Although paper electronics is a compelling concept, the large surface roughness and opaqueness of most paper substrates has hindered its development from a dormant idea to a thriving technology. A recent demonstration of transparent paper with nanoscale surface roughness has revived an interest in using renewable cellulose substrates for electronics and optoelectronics. In this short review, we will first summarize the recent progress of transparent paper electronics through structure engineering. We will also discuss the properties and functionalization of transparent paper, such as surface roughness, printability, thermal stability, etc. Finally, we will summarize the recent achievements on proof-ofconcepts of transparent paper, which pave the way for next-generation green electronics fabricated with roll-to-roll printing methods. Advantages of transparent paper over traditional flexible plastic substrates and its challenges will also be discussed. Broader contextThe mechanical properties of exible electronic devices greatly depend on the substrate that hosts the device. Since the rise of exible electronics in the 1970s, plastics have dominated the industry as the substrate for these devices due to their exibility, lightweight, and durability. A concern with plastics is that they are manufactured from petroleum-based materials and they are not biodegradable, making them environmentally hazardous to produce and dispose. This has led to a green initiative in pursuit of recyclable or environmentally friendly alternatives to plastic substrates to host exible electronics. A compelling technology that has emerged from recent studies is cellulose-based substrates that offer an earth-abundant, recyclable, and cleanly manufactured option for use in exible devices. The unique layered structure of these paper-based structures enables numerous engineering possibilities and device applications. For instance, the development of transparent paper may usher in a new era of exible optoelectronic devices that are amenable to roll-to-roll printing and are environmentally friendly. Transparent paper has already begun to gain signicant research interest in recent years, which has yielded transparent paper substrates with various tailored optical properties that are engineered for new functionalities and that introduce new exible devices. This review is a summary of the contemporary status and prospected future of transparent paper technology for exible, foldable, and environmentally friendly electronics.
In this work, we report a dielectric nanocomposite paper with layered boron nitride (BN) nanosheets wired by one-dimensional (1D) nanofibrillated cellulose (NFC) that has superior thermal and mechanical properties. These nanocomposite papers are fabricated from a filtration of BN and NFC suspensions, in which NFC is used as a stabilizer to stabilize BN nanosheets. In these nanocomposite papers, two-dimensional (2D) nanosheets form a thermally conductive network, while 1D NFC provides mechanical strength. A high thermal conductivity has been achieved along the BN paper surface (up to 145.7 W/m K for 50 wt % of BN), which is an order of magnitude higher than that in randomly distributed BN nanosheet composites and is even comparable to the thermal conductivity of aluminum alloys. Such a high thermal conductivity is mainly attributed to the structural alignment within the BN nanosheet papers; the effects of the interfacial thermal contact resistance are minimized by the fact that the heat transfer is in the direction parallel to the interface between BN nanosheets and that a large contact area occurs between BN nanosheets.
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