In order to enhance the mechanical strength of Low-E glass, Fluorine-doped tin oxide (FTO) films have to be tempered at high temperatures together with glass substrates. The effects of tempering temperature (600 °C ~ 720 °C) and time (150 s ~ 300 s) on the structural and electrical properties of FTO films were investigated. The results show all the films consist of non-stoichiometric, polycrystalline SnO2 without detectable amounts of fluoride. 700 °C and 260 s may be the critical tempering temperature and time, respectively. FTO films tempered at 700 °C for 260 s possesses the resistivity of 7.54 × 10−4 Ω•cm, the average transmittance in 400 ~ 800 nm of ~80%, and the calculated emissivity of 0.38. Hall mobility of FTO films tempered in this proper condition is mainly limited by the ionized impurity scattering. The value of [O]/[Sn] at the film surface is much higher than the stoichiometric value of 2.0 of pure crystalline SnO2.
In this article, the spin-dependent electronic and transport properties of the armchair boron-phosphorous nanoribbons (ABPNRs) are mainly studied by using the non-equilibrium Green function method combined with the spin-polarized density function theory. Our calculated electronic structures indicate that the edge hydrogenated ABPNRs exhibit a ferromagnetic bipolar magnetic semiconductor property, and that the Si atom doping can make ABPNRs convert into up-spin dominated half metal. The spin-resolved transport property results show that the doped devices can realize 100% spinfiltering function, and that the interesting negative differential resistance phenomenon can be observed. Our calculations suggest that the ABPNRs can be constructed as a spin heterojunction by introducing Si doping partially, and it would be used as a spin-diode for nano-spintronics in future.
Ag-based low-E films with a multilayer construction of top-Si3N4/SnO2/NiCrOx/Ag/ZnO/ NiCrOx/TiO2/under-SiOxNy were deposited on unheated glass by vacuum magnetron sputtering and then post-treated in the glass tempering furnace at 675±25°C for 4 min, 5 min and 6 min, respectively. The effects of tempering time on the surface morphology, optical and micro-mechanical properties have been investigated. The results show that the edge of the particles become vague with the increasing time. After tempering, the transmittance of 550 nm is higher than that of the as-deposited glass of 75.89%. Ag-based Low-E films tempered at 675±25°C for 6 min possess the biggest value of the figure of merit of 6.86×10-3 Ω-1 and exhibits the optimal optoelectronic properties. The composite nanohardness increase from 8.04 GPa to 9.23 GPa and the elastic modulus increases from 62.39 GPa to 84.58 GPa when tempered from 0 min to 6 min.
Ni-based WC composite coatings conducted on the surface of 45 steels by free spraying followed with high frequency induction remelting were investigated. The influences of induction remelting time on properties of the coating were discussed. The wear resistance of the coating and the elemental diffusion cross the interface between the coatings and the substrate were analyzed. The compositions and microstructure of the coating before and after a wear test were characterized by scanning electron microscope with energy dispersive X-ray microanalysis. The results indicate that a coating which is free from crackers and pores composed of Ni-based solid solution and dispersed tungsten carbide is obtained by free spraying and induction remelting. The interface is a white lamellar zone. The mutual diffusion of iron and nickel in the interface proves it’s an atomic bonding between the substrate and the coating. The wear mechanisms of the coated sample are abrasive wear and microplowing. The wear resistance of Ni-based WC composite coatings is superior to that of quenched high carbon steels.
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