Word-of-mouth (WOM) study is extended to the on-line context (eWOM) by examining the informational and normative determinants of the perceived credibility of on-line consumer recommendations. A survey of users of an on-line consumer discussion forum in China substantiated the effects of the determinants, although post-hoc analyses revealed that prior knowledge and involvement level moderate some of them. Implications for research and practice are discussed.KEY WORDS AND PHRASES: Credibility, eWOM, informational and normative infl uence, on-line consumer discussion forum.Following the development of network technology, the Internet is permeating almost every aspect of life. One recent phenomenon is the popularity of on-line consumer discussion forums. These consumer forums have millions of registered members with reportedly high hit rates. For instance, daily visits to the discussion forum of www.it168.com, a popular consumer forum in China, are reported to number more than 9 million (www.gdb2b.cn/company/ corporation_web.asp?id=536/). The attraction of the consumer forum is mainly due to a new form of word-of-mouth (WOM) communication, comprising vast amounts of consumer information on opinions and recommendations on vendors/products from experienced consumers. Researchers often refer to this on-line consumer sharing activity as electronic WOM (eWOM) [32,33]. eWOM connects diverse individual consumers and extends and opens up the WOM network from one's immediate contacts to the entire Internet world. As more people utilize product information from the eWOM network to make purchase decisions, the process by which they evaluate the credibility of online consumer recommendations becomes particularly interesting [32]. This is because eWOM arises from a possibly unlimited number of unknown participants, and the presence of vast amounts of unfi ltered information makes the information validity uncertain [22,23,59]. This could raise readers' suspicions about the believability of the on-line reviews [56]. People tend to deliberate on the credibility of eWOM to a greater extent than traditional WOM when seeking on-line product recommendations and will only take on-line advice that they perceive as credible [68]. Prior study has already demonstrated that credibility is one of the most important antecedents of eWOM adoption [47]. As McKnight and Kacmar noted, information credibility is a vital predictor
A record high OFET hole mobility, as high as 23.7 cm(2) /Vs, is achieved in macroscopic aligned semiconducting polymers. The high mobility is insensitive to the polymer molecular weight. Polymer chains are aligned along the fiber to facilitate intrachain charge transport.
Solution processable semiconducting polymers with excellent film forming capacity and mechanical flexibility are considered among the most progressive alternatives to conventional inorganic semiconductors. However, the random packing of polymer chains and the disorder of the polymer matrix typically result in low charge transport mobilities (10(-5)-10(-2) cm(2) V(-1) s(-1)). These low mobilities compromise their performance and development. Here, we present a strategy, by utilizing capillary action, to mediate polymer chain self-assembly and unidirectional alignment on nanogrooved substrates. We designed a sandwich tunnel system separated by functionalized glass spacers to induce capillary action for controlling the polymer nanostructure, crystallinity, and charge transport. Using capillary action, we demonstrate saturation mobilities with average values of 21.3 and 18.5 cm(2) V(-1 )s(-1) on two different semiconducting polymers at a transistor channel length of 80 μm. These values are limited by the source-drain contact resistance, Rc. Using a longer channel length of 140 μm where the contact resistance is less important, we measured μh = 36.3 cm(2) v(-1) s(-1). Extrapolating to infinite channel length where Rc is unimportant, the intrinsic mobility for poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b']dithiophen-2-yl)-alt-[1,2,5]thiadiazolo[3,4-c]pyridine] (Mn = 140 kDa) at this degree of chain alignment and structural order is μh ≈ 47 cm(2 )v(-1) s(-1). Our results create a promising pathway toward high performance, solution processable, and low-cost organic electronics.
A significant enhancement of efficiency in thieno[3,4-b]-thiophene/benzodithiophene:[6,6]-phenyl C71-butyric acid methyl ester (PTB7:PC70 BM) solar cells can be achieved by methanol treatment. The effects of methanol treatment are shown in an improvement of built-in voltage, a decrease in series resistance, an enhanced charge-transport property, an accelerated and enlarged charge extraction, and a reduced charge recombination, which induce a simultaneous enhancement in open-circuit voltage (Voc), short-circuit current (Jsc), and fill factor (FF) in the devices.
High-performance polymer heterojunction solar cells fabricated from an alternating copolymer of 2,7-silafluorene (SiF) and 4,7-di(2′-thienyl)-2,1,3-benzothiadiazole (DBT) (PSiF-DBT) as the electron donor blended with [6,6]-phenyl-C61-butyric acid methyl ester as the electron acceptor were investigated. A power-conversion efficiency up to 5.4% with an open-circuit voltage of 0.90V, a short-circuit current of 9.5mAcm−2, and a fill factor of 50.7% was achieved under the illumination of AM 1.5G from a calibrated solar simulator (800Wm−2). The field-effect transistors fabricated from PSiF-DBT showed a high hole mobility of ∼1×10−3cm2V−1s−1.
Adopting the emerging technology of printed electronics in manufacturing novel ultrathin flat panel displays attracts both academic and industrial interests because of the challenge in the device physics and the potential of reducing production costs. Here we produce all-solution processed polymer light-emitting diode displays by solution-depositing the cathode and utilizing a multifunctional buffer layer between the cathode and the organic layers. The use of ink-jetted conducting nanoparticles as the cathode yields high-resolution cathode patterns without any mechanical stress on the organic layers. The buffer layer, which offers the functions of solvent-proof electron injection and proper affinity, is fabricated by mixing the water/alcohol-soluble polymer and a curable epoxy adhesive. Our 1.5-inch polymer lightemitting diode displays are fabricated without any dead pixels or dead lines. The all-solution process eliminates the need for high vacuum for thermal evaporation of the cathode, which paves the way to industrial roll-to-roll manufacturing of flat panel displays.
The effects of solvent additive (1,8‐diiodooctane (DIO)) on the morphology, charge generation, transport, and recombination in solution‐processed small‐molecule solar cells are studied and these parameters are correlated with device performance. In the optimum nanoscale morphology, which is processed with 0.4% DIO, the phase separation is large enough to create a percolating pathway for carrier transport, yet still small enough to form large interfacial area for efficient charge separation. Complete phase separation in this film reduces the interfacial defects, which occurs without DIO, and hence suppresses the monomolecular recombination. Moreover, balanced charge transport and weak bimolecular recombination lead to a high fill factor (72%). On the other hand, an excess amount of DIO (0.8%) in the solvent results in the over‐aggregation of the donor phase, which disturbs the percolating pathway of the acceptor phase and reduces the electron mobility. The over‐aggregation of the donor phase also shrinks the interfacial area for charge separation and consequently reduces the photocurrent generation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.