The procedures for analyzing pharmaceuticals and personal care products (PPCPs) are typically tedious and expensive and thus, it is necessary to synthesize all available information from previously conducted research. An extensive collection of PPCP data from the published literature was compiled to determine the occurrence, pathways, and the effectiveness of current treatment technologies for the removal of PPCPs in water and wastewater. Approximately 90% of the compiled published papers originated from Asia, Europe, and the North American regions. The incomplete removal of PPCPs in different water and wastewater treatment processes was widely reported, thus resulting in the occurrence of PPCP compounds in various environmental compartments. Caffeine, carbamazepine, diclofenac, ibuprofen, triclosan, and triclocarban were among the most commonly reported compounds detected in water and solid matrices. Trace concentrations of PPCPs were also detected on plants and animal tissues, indicating the bioaccumulative properties of some PPCP compounds. A significant lack of studies regarding the presence of PPCPs in animal and plant samples was identified in the review. Furthermore, there were still knowledge gaps on the ecotoxicity, sub-lethal effects, and effective treatment processes for PPCPs. The knowledge gaps identified in this study can be used to devise a more effective research paradigm and guidelines for PPCP management.
Stormwater runoff monitoring was carried out from 2011 to 2015 to investigate the relationships between rainfall conditions (antecedent dry days (ADDs), rainfall intensity, depth and duration), and water quality parameters of stormwater from a paved road in Korea. Factor analysis suggested that the effect of rainfall conditions on the concentrations of selected pollutants varied depending on the pollutant. As total COD (total chemical oxygen demand) concentration increased, the level of heavy metals increased and resulted in a decrease of BOD 5 (biochemical oxygen demand) because of their toxicity. In addition, ADDs had a significant impact on the wash-off of solids from paved road. The predominant particles in stormwater were 30 µm and smaller, and increased in concentration as ADDs increased. Thus, the initial load of accumulated particles became a major factor in the wash-off process. The mass of particle-related pollutants was also subject to the effect of ADDs due to the affinity between pollutants and predominant particles (<30 µm). However, the effect of ADDs on the mass of organic matter and nitrogen was relatively weak. ADDs contributed to the decrease of some pollutants by photo-oxidation, volatilization and natural decay over dry days, as well as desorption from solids during rainfall.
This study was conducted to develop a vertical subsurface flow (VSF) wetland remediation system packed with woodchips to control stormwater pollution arising from livestock agriculture. Three lab-scale VSF wetlands were operated with recirculation during the interval (Δ) between storms as 2, 4 and 8 days, respectively. The fed water was 100% recirculated one time per 24 h; the recirculation frequency was 1, 3 and 7 times at Δ of 2, 4 and 8 days, respectively. The constructed wetland systems proved to be effective in reducing total suspended solid (TSS), but also had potential for increasing TSS in the effluent due to the properties of the woodchips. The release of organic matter, especially in the dissolved form, occurred during the initial 60 days. The removal efficiencies of total nitrogen (TN) were 26.2%, 34.1% and 50.0% at Δ of 2, 4 and 8 days, respectively. Nitrification was promoted by the abundant oxygen supplied when the water in wetland was recirculated and fed into the wetland. Denitrification was stable and effective due to the availability of carbon sources. The influent total phosphorus (TP) was reduced from an average of 2.05 mg L(-1) to 1.79 mg L(-1), 1.36 mg L(-1) and 0.86 mg L(-1) at Δ as 2, 4 and 8 days, respectively. The result shows that woodchips can be used as substrate material for VSF wetland treatment systems to control nutrient influx from livestock stormwater.
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