The emission of greenhouse gases, including high CO2 and other materials, initiates global warming and climate change. Atmospheric CO2 that affects the carbonate system of seawater causes ocean acidification (OA). OA affects marine organisms directly, as well as humans economically and ecologically. Considering the high impact of OA and following the United Nations' Sustainable Development Goals, systematic research and monitoring of OA is necessary in Indonesia, whose seas play an important role in this emerging phenomenon. This review discusses the urgency of OA monitoring systems and suggests carbonate system monitoring, as well as carbon biogeochemistry. OA significantly affects marine production and alters ecosystem services, and it is likely to have an impact on habitats shifting from calcified to non-calcified and reducing benthic complexity. Its effect on calcifying organisms can also be found, i.e., coral calcification and/or dissolution of CaCO3 of calcifying organisms. Acidity (pH), as well as the carbonate system variables of seawater, fluctuate, especially with variations in space and time. Coastal ecosystems that are directly affected by terrestrial input will have carbonate system variables that fluctuate more. The annual rate of decreasing seawater pH, especially over an open and large spatial scale, may indicate OA. Therefore, a monitoring system must be implemented to obtain systematic and comprehensive information on OA. Here, we also introduce a biogeochemical monitoring initiative for OA in Lombok with the established protocols. Improvement of many aspects, including analysis instruments, analysis methods, sample treatment, and sampling frequency will provide new insight into further research and monitoring of OA.
The biogeochemical cycle of trace metals is very likely affected by the global change in the ocean, especially due to the increasing of sea surface temperature and acidity. Thus, assessing biogeochemical cycle of trace metals will beneficial in elucidating the potential impact of climate change as well as ocean acidification. The assessment of the biogeochemical cycle of trace metals can be performed by measuring trace metals fluxes crossing the sediment-water interface. The main challenge in this measurement is the difficulty of measuring metal concentrations at trace levels due to either physical factors or biological factors that can affect the total flux. Sediment porewater profile and in situ benthic incubation are the two most commonly used methods for measuring trace metals fluxes from sediment to the overlying water or vice versa. The coefficient of diffusion and gradient of concentration are the two most important values in the sediment porewater profile method, while the constant volume involved in the container during the experiment is an important part of the in situ benthic incubation method. The purpose of this review is to provide an overview of both measurement methods deeply and predict the challenges faced in its implementation in Indonesia.
Keywords: Benthic fluxes; Overlying water; Porewater; Sediment; Trace metals
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