The strategy of band convergence of multi-valley conduction bands or multi-peak valence bands has been widely used to search or improve thermoelectric materials. However, the phonon-assisted intervalley scatterings due to...
By using a first-principles approach, monolayer PbI 2 is found to have great potential in thermoelectric applications. The linear Boltzmann transport equation is applied to obtain the perturbation to the electron distribution by different scattering mechanisms. The mobility is mainly limited by the deformation-potential interaction with long-wavelength acoustic vibrations at low carrier concentrations. At high concentrations, ionized impurity scattering becomes stronger. The electrical conductivity and Seebeck coefficient are calculated accurately over various ranges of temperature and carrier concentration. The lattice thermal conductivity of PbI 2 , 0.065 W/mK at 300 K, is the lowest among other 2D thermoelectric materials. Such ultralow thermal conductivity is attributed to large atomic mass, weak interatomic bonding, strong anharmonicity, and localized vibrations in which the vast majority of heat is trapped. These electrical and phonon transport properties enable high thermoelectric figure of merit over 1 for both p-type and n-type doping from 300 K to 900 K. A maximum zT of 4.9 is achieved at 900 K with an electron concentration of 1.9×10 12 cm −2 . Our work shows exceptionally good thermoelectric energy conversion efficiency in monolayer PbI 2 , which can be integrated to the existing photovoltaic devices.
arXiv:1811.04244v2 [cond-mat.mtrl-sci]Organic-inorganic CH 3 NH 3 PbI 3 perovskite solar cells have emerged as a leading next-generation photovoltaic technology 1-10 . As the precursor material used to fabricate perovskite thin films 11-20 , lead iodide (PbI 2 ) leads to remarkable advances in efficiency due to the 6s 2 electronic configuration of Pb 21 . Encapsulated perovskite devices with excess PbI 2 exhibit good stability 22 . An excess of PbI 2 is beneficial to a better crystallization of the perovskite layer and improves the performance of perovskite solar cells [23][24][25][26] . After long exposures, CH 3 NH 3 PbI 3 eventually forms PbI 2 due to its instability in moist air [27][28][29][30][31] . According to this degradation process, waste PbI 2 at the end of its useful life can be recycled using an appropriate solvent 32,33 . Therefore, although CH 3 NH 3 PbI 3 perovskite has a drawback in the toxicity of lead 34-36 , the perovskite technology can be deployed in a completely safe way by recycling PbI 2 .After absorbing solar energy, the photo-induced carriers are generated in the CH 3 NH 3 PbI 3 region, while the PbI 2 passivation layers can prevent back recombination and facilitate charge separation 37 . Besides the sunlight collected by the perovskite solar cells, a large fraction of solar energy is converted into heat in the form of phonons as well 38 . Such heat can be converted into electricity by thermoelectric materials when the temperature gradient is generated. Here we show for the first time that PbI 2 itself is a promising candidate for high-efficiency thermoelectric applications.The fabrication of PbI 2 nanostructures is being pursued with increasing interest in chemistry, physics,...
The emerging semiconductor boron arsenide (BAs) with high thermal conductivity attracts much attention recently, due to its promising application to overcome the bottleneck of high-density heat generated in power electronics...
The band-convergent strategy by improving density of states effective masses has been proposed and successfully used in past decades to optimize thermoelectric performance in materials or discover new thermoelectric materials....
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