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Different photoinactivation ways resulting from different crystal packing may account for different photochromic and fluorescence properties of the title polymorphs.

The authors used a nitric acid (HNO3)-sodium dodecyl benzene sulfonate (SDBS) method to modify a lignite-based activated carbon. These modified carbons were appraised for their removal of Cd(II) from aqueous solutions. Response surface methodology was employed to optimize the preparation factors including nitric acid concentration CN, temperature T and SDBS concentration CS. Statistical analysis indicated that the interaction of CN and CS incurred the most effect on the maximum cadmium adsorption capacity (Qm). The optimal Qm appeared at CN = 3.29 mol/L, T = 76 °C and CS=30,700 mg/L. The optimal protocol achieved 44.21 mg/g Qm for Cd(II) which was about 7 times larger than for this pristine lignite activated carbon (LAC) (6.78 mg/g). The physical-chemical properties of the modified activated carbons following each synthesis step were characterized relative to their surface area, oxygen functionality, and external surface charge. It was confirmed that the developed surface area, functional groups and negative charges were mainly responsible for the higher adsorption capacity for the LAC that have been more favorably tailored by this HNO3-SDBS protocol.

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Coke plant wastewater (CPW) is an intractable chemical wastewater, and it contains many toxic pollutants. This article presents the results of research on a semi-industrial adsorption method of coking wastewater treatment. As a sorbent, the coking coal (CC) was a dozen times less expensive than active carbon. The treatment was conducted within two scenarios, as follows: (1) adsorption after biological treatment of CPW with CC at 40 g L(-1); the chemical oxygen demand (COD) removal was 75.66%, and the concentration was reduced from 178.99 to 43.56 mg L(-1); (2) given an adsorption by CC of 250 g L(-1) prior to the biological treatment of CPW, the eliminations of COD and phenol were 58.08% and 67.12%, respectively. The CC that adsorbed organic pollution and was returned to the coking system might have no effect on both coke oven gas and coke.

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