In this paper, the authors consider the processes of dynamic interaction between the boiling particles of the dispersed phase of the emulsion leading to the large droplet breakup. Differences in the consideration of forces that determine the breaking of non-boiling and boiling droplets have been indicated in the study. They have been determined by the possibility of using the model to define the processes of displacement, deformation, or fragmentation of the inclusion of the dispersed phase under the influence of a set of neighboring particles. The dynamics of bubbles in a compressible liquid with consideration for interfacial heat and mass transfer has also been analyzed in the paper. The effect of standard and system parameters on the intensity of cavitation processes is considered. Physical transformations during the cavitation treatment of liquid are caused not only by shock waves and radiated pressure pulses but also by extreme thermal effects. At the stage of ultimate bubble compression, vapor inside the bubble and the liquid in its vicinity transform into the supercritical fluid state. The model analyzes microflow features in the inter-bubble space and quantitatively calculates local values of the velocity and pressure fields, as well as dynamic effects.

Heat pumps are the ideal solution for powering new passive and low-energy buildings, as geothermal resources provide buildings with heat and electricity almost continuously throughout the year. Among geothermal technologies, heat pump systems with vertical well heat exchangers have been recognized as one of the most energy-efficient solutions for space heating and cooling in residential and commercial buildings. A large number of scientific studies have been devoted to the study of heat transfer in and around the ground heat exchanger. The vast majority of them were performed by numerical simulation of heat transfer processes in the soil massif–heat pump system. To analyze the efficiency of a ground heat exchanger, it is fundamentally important to take into account the main factors that can affect heat transfer processes in the soil and the external environment of vertical ground heat exchangers. In this work, numerical simulation methods were used to describe a mathematical model of heat transfer processes in a porous soil massif and a U-shaped vertical heat exchanger. The purpose of these studies is to determine the influence of the filtration properties of the soil as a porous medium on the performance characteristics of soil heat exchangers. To study these problems, numerical modeling of hydrodynamic processes and heat transfer in a soil massif was performed under the condition that the pores were filled only with liquid. The influence of the filtration properties of the soil as a porous medium on the characteristics of the operation of a soil heat exchanger was studied. The dependence of the energy characteristics of the operation of a soil heat exchanger and a heat pump on a medium with which the pores are filled, as well as on the porosity of the soil and the size of its particles, was determined.

The article presents studies of the influence of parameters of synthesis modes and alkali concentration on the synthesis of zeolite materials from coal fly ash (CFA). The purpose of the study was to synthesise zeolite materials from CFA using the method of alkaline fusion and to determine the susceptibility of selected heavy-metal ions to removal from solutions in an ion exchange process on a selected mesoporous zeolite. It was found that the crystalline phase of sodalite was dominated in all of the samples synthesized. The specific surface area (SBET) of the samples was evaluated using the standard Brunauer–Emmett–Teller (BET) method using N2 sorption. Crystalline zeolite materials have been used to study the efficiency of removing heavy metals from aqueous solutions of Ni2+, Cd2+ and Pb2+. The adsorption data were analyzed using the Langmuir and Freundlich isotherm model. When comparing the estimated coefficient of determination (r2), it was noticed that the sorption data are more accurately described by the Langmuir isotherm and the pseudo-second-order kinetic model. The results of metal adsorption experiments suggest that the synthesized zeolite material has great potential to be used as an inexpensive and alternative source in the production of adsorbents.

This paper presents the analysis of the main reasons for a significant decrease in the intensity of diffusion processes during the formation of gas hydrates; solutions to this problem are proposed in a new process flow diagram for the continuous synthesis of gas hydrates. The physical processes, occurring at the corresponding stages of the process flow, have been described in detail. In the proposed device, gas hydrate is formed at the boundary of gas bubbles immersed in cooled water. The dynamic effects arising at the bubble boundary contribute to the destruction of a forming gas hydrate structure, making it possible to renew the contact surface and ensure efficient heat removal from the reaction zone. The article proposes an assessment technique for the main process parameters in the synthesis of hydrates based on the criterion of thermodynamic parameters optimization. The optimization criterion determines the relationship of intensity of heat and mass transfer processes at the phase contact interface of reacting phases, correlating with the maximum GH synthesis rate, and makes it possible to determine optimum thermodynamic parameters in the reactor zone.

The improvement of the thermal insulating material thermophysical characteristics of the thermal protection elements by studying the porous structure is a promising direction of research. The article describes the effects of the porosity and coupling of the porous structure on the thermophysical characteristics of thermal insulating materials. The article uses standard systematized techniques and instruments of scientific research applied in thermophysics. The research methodology of highly-porous material thermophysical properties is based on performance of empirical laboratory investigations of the samples obtained. It was found that for the pore structure effect on the material characteristics it is rational to use the following complex indices: porosity, number of pores, pore position in space, the pore form, pore formation energy. The article shows the effect of the porous structure on the thermophysical characteristics of the material. The complex parameters of the porous structure, which will allow to develop a new method of control of the porous structure, are proposed. As a result of the experiment planning method, the regression equation of an effective coefficient of thermal conductivity for porous thermal protection structures was developed. It was established that for a more even distribution of the mixture in a volume it is necessary to minimize the size of the dispersed components, thereby increasing the area of their contacts. The experimental method revealed that the moisture evaporation caused the formation of pores inside the clay. The shape of the pores was determined using electron microscope MMP-2P, both on the sample section and surface. The clearest clay has the greatest porosity (no iron oxide and calcium oxide). The pores have a spherical shape in it. The presence of impurities reduces the material porosity due to the increased clay viscosity.

The study of the porosity of thermal insulation made of refractory materials is an important task for the power industry, since the thermal conductivity of porous materials depends on the shape and especially the location of the pores. An analytical review of existing technologies shows that research in this area is not enough to simulate the process of heat and mass transfer in porous alumina material. Experimental determination of the characteristics of heat and mass transfer in porous materials during the formation of a porous structure is a pressing scientific problem. This article analyzes the influence of the composition of materials on the formation of pores, as well as the effect of various impurities and temperature on the thermal conductivity of the material.

The article discusses the physicochemical mechanisms of the effect of chemical reagents on the processes of swelling of the raw mixture based on the ash of thermal power plants. The process of structure formation in such mixtures occurs as a result of physicochemical transformations of its constituent components. To intensify gas evolution and obtain materials of a porous structure, the presence of a gas former is necessary. The author has analysed the possibility of creating a porous structure in a raw mixture based on ash with the introduction of various gas formers or their formation as a result of exchange reactions. The main chemical compounds contributing to pore formation have been determined. To form a given structure, it is proposed to control chemical transformations at the stage of swelling. To study the processes of intensification of gas evolution, the author proposes to investigate the mechanisms of the influence of mineral fillers and chemical reagents on swelling processes based on the analysis of the Gibbs equation. The parameters of the Gibbs equation are obtained, by which it is possible to determine the probability of the occurrence of chemical reactions with the proposed chemical agents for the formation of gas bubbles with (pores) in the raw material.

This paper focuses on the application of speed-regulated compressors (SRCs) to cover changeable heat loads with high efficiency in conventional air conditioning systems (ACS) as well as in the more advanced variable refrigerant flow (VRF)-type outdoor and indoor ACS. In reality, an SRC is an oversized compressor, although it can operate efficiently at part loads. The higher the level of regulated loads (LRL) of the SRC, the more the compressor is oversized. It is preferable to reduce the size of the SRC by covering the peak loads and recouping the excessive refrigeration energy reserved at decreased actual loads within the range of regulated loads. Therefore, the range of changeable loads is chosen as the object to be narrowed by using the reserved refrigeration capacity. Thus, the general fundamental approach of dividing the overall heat load range of the ACS into the ranges with changeable and unchangeable loads, as previously developed by the authors, is applied for the range of primary changeable loads. Due to this innovative step, the principle of two-stage outdoor air conditioning according to changeable and unchangeable loads, also proposed by the authors, has been extended over the range of primary changeable loads to reduce the level of refrigeration capacity regulation and SRC size. To realize this, part of the changeable load range is offset by the reserved refrigeration capacity, leading to a reduction in the changeable load range and the SRC size by approximately 20% for temperate climatic conditions.