A special composite of the cerium-based metal–organic framework (Ce-UiO-66) modified with graphitic carbon nitride nanosheets (g-C3N4) has been synthesized. In order to make a comparison, a series of composites comprising...
HKUST‐1‐Cu synthesized in the presence and absence of P‐123 trough solvotermal method. After characterization using some different microscopic and spectroscopic techniques such as XRD, FT‐IR, SEM, ICP, BET and TEM its catalytic activity was investigated in the oxidative coupling of benzyl alcohol, benzaldhyde, benzoic acid, styrene and phenyl acetylene with N,N‐dialkylformamides for the preparation of N,N‐dimethylformamides. Different derivatives of tertiary amides were synthesized in moderate to good yields in the presence of just ~0.28 mol% of this catalytic system. Reusability of the synthesized catalysts was examined and catalysts were reusable for 8 times without significant decrease in optimized conditions.
FeIII-based metal-organic framework denoted as MIL-100(Fe) coated with cobalt-aluminum layered double hydroxide (CoAl-LDH) nanoplates have been synthesized. Their structural information was obtained through Powder X-ray Diffraction (PXRD), Fourier transforms infrared...
Correction for ‘g-C3N4@Ce-MOF Z-scheme heterojunction photocatalyzed cascade aerobic oxidative functionalization of styrene’ by Meghdad Karimi et al., New J. Chem., 2021, 45, 6671–6681, DOI: 10.1039/D1NJ00120E.
Considering the irreplaceable importance of photocatalytic functionalization reactions and the widespread attention paid to the use of metal-organic frameworks, especially their modified variants for this purpose in recent years, different...
In metal–organic frameworks, confined space as a chemical nanoreactor is as important as organocatalysis or coordinatively unsaturated metal site catalysis.
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