g-C₃N₄@Ce-MOF Z-scheme heterojunction photocatalyzed cascade aerobic oxidative functionalization of styrene

Abstract

A special composite of the cerium-based metal–organic framework (Ce-UiO-66) modified with graphitic carbon nitride nanosheets (g-C3N4) has been synthesized. In order to make a comparison, a series of composites comprising...

Advances in Hybrid Composites for Photocatalytic Applications: A Review

“…Until now, many semiconductors have been reported to form composites with MOFs. Metal-containing semiconductors (such as ZnO [ 155 ], TiO 2 [ 156 ], BiVO 4 [ 157 ], and CdS [ 158 ]) and non-metal graphitic carbon nitride [ 159 ] have been reported to form composites with MOFs exhibiting highly potential performance in the field of photocatalysis.…”

Confined-based catalyst investigation through the comparative functionalization and defunctionalization of Zr-MOF

“…16–18 These structures act as nanoreactors to perform chemical reactions, which lead to more effective collisions and more likely reactions due to size and shape selectivity towards reactants, transition states, and products. 19–26 Secondly, regarding the functional groups and the spatial effects, electronic effects are also involved, and the role of functional groups and open metal sites as Lewis acids and bases becomes very significant, especially in condensation reactions. 25,27–29…”

“…19–26 Secondly, regarding the functional groups and the spatial effects, electronic effects are also involved, and the role of functional groups and open metal sites as Lewis acids and bases becomes very significant, especially in condensation reactions. 25,27–29…”

“…[16][17][18] These structures act as nanoreactors to perform chemical reactions, which lead to more effective collisions and more likely reactions due to size and shape selectivity towards reactants, transition states, and products. [19][20][21][22][23][24][25][26] Secondly, regarding the functional groups and the spatial effects, electronic effects are also involved, and the role of functional groups and open metal sites as Lewis acids and bases becomes very signicant, especially in condensation reactions. 25,[27][28][29] Therefore, MOFs are distinguished candidates for the contemporaneous investigation of structurally and electronically driven catalysis, increasing our knowledge about catalytic reactions.…”

“…[19][20][21][22][23][24][25][26] Secondly, regarding the functional groups and the spatial effects, electronic effects are also involved, and the role of functional groups and open metal sites as Lewis acids and bases becomes very signicant, especially in condensation reactions. 25,[27][28][29] Therefore, MOFs are distinguished candidates for the contemporaneous investigation of structurally and electronically driven catalysis, increasing our knowledge about catalytic reactions. As a result, structural features such as stability in different reaction media, the ability to create diversity while avoiding useless complications, the interactive effect of the catalytic centres and the pore's interior spaces are essential.…”