Amino acid-assisted ferrite/MOF composite formation for visible-light induced photocatalytic cascade C=C aerobic oxidative cleavage functionalization

Non -covalent LDH/MOF composite formation: a new approach in sustainability for solvent-dependent photocatalytic aerobic alcohol oxidation

“…However, since most layered materials show deficiencies, such as a high recombination rate of photogenerated charges and fewer surface active sites, using them brings about lower selectivity and conversion in organic transformations. [27][28][29] Regardless of the above-mentioned layered materials, there are two-dimensional (2D) nanosheets that are quite attractive to chemists due to their specified characteristics, such as nanoscale thickness, plentiful active sites, large surface area, the high speed of charge separation, and significant amounts of unsaturated surface sites, [30][31][32][33] endowing them with high capability in organic synthesis.…”

Confined-based catalyst investigation through the comparative functionalization and defunctionalization of Zr-MOF

“…30,31 It has been concluded that environmentally-friendly MOFs and eco-friendly strategies based on sustainable building blocks are ideal for the intended purpose. [32][33][34][35][36][37] Frameworks based on terephthalic acid and 2-aminoterephthalic acid and iron, aluminium, chromium, cerium and zirconium clusters are essential in catalytic studies due to their unparalleled stability. [38][39][40][41][42][43][44][45][46] Recently, structures based on zirconium and terephthalic acid-based ligands, namely the UiO-66 family, have captured much attention in various applications.…”