Water-ground Phlogopite micas were classified into narrow particle-size distributions containing flakes with well-defined diameters and thicknesses in order to evaluate the influence of particle size and flake aspect ratio on the mechanical properties of mica-filled polypropylenes. For the purposes of comparison, most of the injection-molded specimens contained 40 percent (by weight) mica. As expected, the flexural and tensile modulus values increased in proportion to the aspect ratio over the range from 30 to 60 to a maximum of 8 GPa. The measured tensile strengths of the mica-filled polypropylenes increased substantially as the flake diameter became smaller, but did not correlate with the flake aspect ratio. The attainable properties were frequently dependent upon the method of mixing, and considerable care was necessary to ensure proper dispersion and adequate coupling. Intensive mixing, as in a Gelimat Mixer, may cause in situ delamination and particle-size reduction of the mica filler particles, leading to a marked increase in tensile strength of the resulting composite. The mica-filled compounds could be reprocessed many times without significant loss of properties, particularly compounds having mica particles less than 40 pm in diameter. The fracture energies (notched Izod) and the heat-distortion temperatures were not appreciably influenced by the size or aspect ratios of the mica within this range. Increased fracture toughness could be achieved by reducing the mica concentration or employing a polypropylene copolymer. Guidelines are presented to indicate the preferred characteristics of mica fillers and the influence of mixing conditions on performance.
Experiments carried out on pultruded fibre reinforced polyester resins show that, at moderate fibre volume fractions, the compressive strength of aligned fibre composites depends linearly on the volume fraction. The strength falls off when the fibre volume fraction, Vf = 0.4 with Kevlar and high strength carbon fibres; The effective fibre strength at Vf < 0.4 is much less than the tensile strength but it is close to the tensile strength with E-glass fibres and high modulus carbon fibres. Poor adhesion between fibres and matrix reduces the compressive strength, as does kinking the fibres when the fibre radius of curvature is reduced to below 5 mm. Misalignment of the fibres reduces the compressive strength when the average angle of misalignment exceeds about 10 ~ for glass and carbon fibres. However, with Kevlar no such reduction is observed because the compression strength of Kevlar reinforced resin is only a very little better than that of the unreinforced resin.
Water‐ground Phlogopite mica (Kemira Siilinjarvi phlogopite) has been evaluated as a reinforcing filler in polypropylene. The major factors which influence the composite strength and modulus include the size, aspect ratio, and uniformity of the mica flakes. Aqueous delamination permits the production of very small flakes (less than 44 microns diameter) with aspect ratios near 50. Such small flakes impart greater tensile and modulus values to polypropylene than larger flakes and the former can also be reprocessed many times without any deterioration of properties. Surface treatment is necessary for adequate dispersion and coupling, particularly with the finely divided mica fillers. Other properties such as the heat‐distortion temperature, fracture toughness, and gas permeability are also influenced by the mean size and aspect ratio of the mica filler. Guidelines are presented to indicate the preferred characteristics of mica fillers for optimum performance.
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