The complex performance of newly synthesized CoNiMnB electrodeposits in base-stabilized sodium borohydride solutions was examined. The rate of hydrogen generation due to borohydride hydrolysis was determined at different temperatures. Activation energy of approximately 33 kJ/mol was estimated, which is lower than the values reported for other catalysts. At electrochemical conditions, there is a competition between borohydride hydrolysis and electrooxidation reactions. The electrooxidation of borohydride takes place with low overpotentials at relatively high current densities. The long-term discharge at galvanostatic conditions as well as possibilities for partial storage of generated hydrogen indicates potentials for application of studied electrodeposits as anode material in direct borohydride fuel cells (DBFC).
In the recent years, robotic systems became more advanced and more accessible. This has led to their slow, but stable integration and use in different processes and applications, including in the agricultural domain. Nowadays, agricultural robots are developed with the aim to replace the human labour in the otherwise exhausting, time-consuming or dangerous activities. Agricultural robotic systems provide many advantages, which can differ based on the type of the robot and its sensors, actuators and communication systems. This paper presents the design, the construction process, the main characteristics and the evaluation of a prototype of a small-scale agricultural robot that can be used for some of the simplest activities in agricultural enterprises. The robot is designed as an end-user autonomous mobile system, which is capable of self-localization and can map or inspect a specific farming area. The decision-making capabilities of the robot are based on artificial intelligence (AI) algorithms, which allow it to perform specific actions in accordance to the situation and the surrounding environment. The presented prototype is in its early development and evaluation stages and the paper concludes with discussions on the possible further improvements of the platform.
Pd-Au codeposits with different ratio of both metals were electrodeposited on carbon felt, characterized by scanning electron microscopy, and investigated as electrocatalysts towards hydrogen evolution reaction in neutral phosphate buffer solution. The quantities of the produced hydrogen gas with different electrocatalysts, estimated from data obtained by chronoamperometry, were confirmed by mass spectrometry analysis. The highest hydrogen evolution rate was achieved with the electrocatalysts, produced from electrolyte with equal Pd and Au content.
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