Piezoelectric actuators are indispensable over a wide range of industries for their fast response and precise displacement. Most commercial piezoelectric actuators contain lead, posing environmental challenges. We show that a giant strain (1.05%) and a large-signal piezoelectric strain coefficient (2100 picometer/volt) are achieved in strontium (Sr)–doped (K,Na)NbO 3 lead-free piezoceramics, being synthesized by the conventional solid-state reaction method without any post treatment. The underlying mechanism responsible for the ultrahigh electrostrain is the interaction between defect dipoles and domain switching. The fatigue resistance, thermal stability, and strain value (0.25%) at 20 kilovolt/centimeter are comparable with or better than those of commercial Pb(Zr,Ti)O 3 -based ceramics, showing great potential for practical applications. This material may provide a lead-free alternative with a simple composition for piezoelectric actuators and a paradigm for the design of high-performance piezoelectrics.
For traditional piezoelectric sensors based on poled ceramics, a low curie temperature (Tc) is a fatal flaw due to the depolarization phenomenon. However, in this study, we find the low Tc would be a benefit for flexible piezoelectric sensors because small alterations of force trigger large changes in polarization. BaTi0.88Sn0.12O3 (BTS) with high piezoelectric coefficient and low Tc close to human body temperature is taken as an example for materials of this kind. Continuous piezoelectric BTS films were deposited on the flexible glass fiber fabrics (GFF), self-powered sensors based on the ultra-thin, superflexible, and polarization-free BTS-GFF/PVDF composite piezoelectric films are used for human motion sensing. In the low force region (1–9 N), the sensors have the outstanding performance with voltage sensitivity of 1.23 V N−1 and current sensitivity of 41.0 nA N−1. The BTS-GFF/PVDF sensors can be used to detect the tiny forces of falling water drops, finger joint motion, tiny surface deformation, and fatigue driving with high sensitivity. This work provides a new paradigm for the preparation of superflexible, highly sensitive and wearable self-powered piezoelectric sensors, and this kind of sensors will have a broad application prospect in the fields of medical rehabilitation, human motion monitoring, and intelligent robot.
Transparent ferroelectrics, with promising prospects in transparent optoelectronic devices, have unique advantages in self-powered photodetection. The self-powered photodetectors based on the photovoltaic effect have quicker responses and higher stability compared with those based on the pyroelectric effect. However, the ferroelectric ceramics previously applied are always opaque and have no infrared light-stimulated photovoltaic effect. Thus, it would be very meaningful to design photodetectors based on infrared light-stimulated photovoltaic effect and/or transparent ferroelectric ceramics. In this work, highly optical transparent pristine lead lanthanum zirconate titanate (PLZT) and band gap-engineered Ni-doped PLZT ceramics with excellent piezoelectric/ferroelectric properties were prepared by hot-pressing sintering. Stable and excellent photovoltaic performance was obtained for pristine PLZT and band gap-engineered PLZT. The value of short-circuit current density is at least 2 orders of magnitude larger than those in PLZT reported in previous works. The transparent PLZT and Ni-doped PLZT ferroelectric ceramics are applied as self-powered photodetectors for the first time for 405 nm and near-infrared light, respectively. The devices based on PLZT under 405 nm light exhibit high detectivity (7.15 × 10 7 Jones) and quick response (9.5 ms for rise and 11.5 ms for decay), and those devices based on Ni-doped PLZT, under near-infrared light filtered from AM 1.5 G simulated sunlight, also exhibit high detectivity (6.86 × 10 7 Jones) and short response time (8.5 ms), both presenting great potential for future transparent photodetectors.
Bandgap engineered ferroelectrics have raised the utmost interest in achieving visible/near-infrared light utilization. The gap states in ferroelectrics can not only realize the absorption of visible/near-infrared light but also keep their excellent piezoelectricity. However, the impurity energy levels provide limited photogenerated carrier, and the doping ions may act as trapping sites, which make it difficult to convert enough sunlight to chemical or electrical energy. In this work, we report a novel strategy to achieve the cooperative interaction of codopants and significantly enhance the photocatalytic activity of the host ferroelectrics. The (N3–, Ni2+)-codoped (Na0.5Bi0.5)TiO3–BaTiO3 composition was taken as the concrete example, which has a lower bandgap of 2.06 eV without gap state. Largely enhanced photocatalytic activity including organic pollutant degradation and photocatalytic oxidative desulfurization were realized, in which the photodegradation efficiency of RhB was increased by 250% and dibenzothiophene could be degraded to lower than 10 ppm within 150 min. Moreover, a long-standing confusion about the appearance/disappearance of bandgap state in transition-metal-doped ferroelectrics has been properly clarified based on theoretical calculation result. Our work could provide a new insight for advancing the bandgap engineering and improving the energy conversion efficiency.
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