Both conductivity and mobility are essential to charge transfer by carrier transport layers (CTLs) in perovskite solar cells (PSCs). The defects derived from generally used ionic doping method lead to the degradation of carrier mobility and parasite recombinations. In this work, a novel molecular doping of NiO hole transport layer (HTL) is realized successfully by 2,2'-(perfluoronaphthalene-2,6-diylidene)dimalononitrile (F6TCNNQ). Determined by X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy, the Fermi level (E ) of NiO HTLs is increased from -4.63 to -5.07 eV and valence band maximum (VBM)-E declines from 0.58 to 0.29 eV after F6TCNNQ doping. The energy level offset between the VBMs of NiO and perovskites declines from 0.18 to 0.04 eV. Combining with first-principle calculations, electrostatic force microscopy is applied for the first time to verify direct electron transfer from NiO to F6TCNNQ. The average power conversion efficiency of CsFAMA mixed cation PSCs is boosted by ≈8% depending on F6TCNNQ-doped NiOx HTLs. Strikingly, the champion cell conversion efficiency of CsFAMA mixed cations and MAPbI -based devices gets to 20.86% and 19.75%, respectively. Different from passivation effect, the results offer an extremely promising molecular doping method for inorganic CTLs in PSCs. This methodology definitely paves a novel way to modulate the doping in hybrid electronics more than perovskite and organic solar cells.

The continuous-variable version of quantum key distribution (QKD) offers the advantages (over discrete-variable systems) of higher secret key rates in metropolitan areas, as well as the use of standard telecom components that can operate at room temperature. An important step in the real-world adoption of continuous-variable QKD is the deployment of field tests over commercial fibers. Here we report two different field tests of a continuousvariable QKD system through commercial fiber networks in Xi'an and Guangzhou over distances of 30.02 km (12.48 dB) and 49.85 km (11.62 dB), respectively. We achieve secure key rates two orders-of-magnitude higher than previous field test demonstrations by employing an efficient calibration model with one-time evaluation. This accomplishment is also realized by developing a fully automatic control system which stabilizes system noise, and by applying a rate-adaptive reconciliation method which maintains high reconciliation efficiency with high success probability in fluctuated environments. Our results pave the way to deploy continuousvariable QKD in metropolitan settings.

Two-dimensional (2D) layered transition-metal dichalcogenides (LTMDs) display various crystal phases with distinct symmetries, structures, and physical properties. Exploring and designing different structural phases in two dimensions could provide an avenue for switching material properties, aiming at practical applications for potential fields. Here we demonstrate a conceptually designed approach to narrow the band gap of MoSe and obtain a conductive red MoSe nanosheet. By introducing the high valence state of Mo species and constructing the Mo-O bonding on the surface of the MoSe nanosheets, the electronic properties can be modified and the conductivity is accordingly improved, an effect that significantly improves their lithium storage capacity and high-rate capability. We anticipate that the exploration of the conductive red MoSe with tunable band gap could help us unlock more potential crystal structures of LTMD-based and even other 2D materials for further applications.

Measurement-device-independent quantum key distribution protocol, whose security analysis does not rely on any assumption on the detection system, can immune the attacking against detectors. We give a first composable security analysis for continuous-variable measurement-device-independent quantum key distribution using squeezed states against general coherent attacks. The security analysis is derived based on the entanglement-based scheme considering finite size effect. A version of entropic uncertainty relation is exploited to give a lower bound on the conditional smooth minentropy by trusting Alice's and Bob's devices. The simulation results indicate that, in the universal composable security framework, the protocol can tolerate 2.5 dB and 6.5 dB channel loss against coherent attacks with direct and reverse reconciliation, respectively.

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We have investigated the anisotropic magnetic responses of a 2D-superconducting Bi2Te3/FeTe heterostructure. Cross-sectional STEM imaging revealed that the excess Fe atoms in the FeTe layer occupy specific interstitial sites. They were found to show strong anisotropic magnetic responses under a magnetic field either perpendicular or parallel to the sample surface. Under perpendicular magnetic fields within 1000 Oe, conventional paramagnetic Meissner effect, superconducting diamagnetism, and anomalous enhancement of magnetization successively occur as the magnetic field increases. In contrast, under parallel magnetic fields, superconducting diamagnetism was not observed explicitly in the magnetization measurements and the anomalous enhancement of magnetization appears only for fields higher than 1000 Oe. The observed strong magnetic anisotropy provides further evidence that the induced superconductivity at the interface of the Bi2Te3/FeTe heterostucture has a 2D nature.

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We consider the noisy thermal amplifier channel, where signal modes are amplified together with environmental thermal modes. We focus on the secret-key capacity of this channel, which is the maximum amount of secret bits that two remote parties can generate by means of the most general adaptive protocol, assisted by unlimited and two-way classical communication. For this channel only upper and lower bounds are known, and in this work we improve the lower bound. We consider a protocol based on squeezed states and homodyne detections, in both direct and reverse reconciliation. In particular, we assume that trusted thermal noise is mixed on beam splitters controlled by the parties in a way to assist their homodyne detections. The new improved lower bounds to the secret-key capacity are obtained by optimizing the key rates over the variance of the trusted noise injected, and the transmissivity of the parties' beam splitters. Our results confirm that there is a separation between the coherent information of the thermal amplifier channel and its secret key capacity.We now present a QKD protocol whose key rate in DR and RR improves the lower bound in Eq. (4). Even though the improvement found is small, it is meaningful because it shows that the coherent information of the thermal amplifier channel is cannot be its secret key capacity. First we derive the new achievable rates in subsections 3.1 and 3.2. Then we numercally compare the results in subsection 3.3.