The thermodynamic performance of several condensation cycles employing carbon dioxide as working medium is analyzed and discussed. A balanced distribution of thermodynamic losses between mechanical components and heat exchangers attained through a compression performed partially in the liquid and partially in the gas phase yields cycle efficiencies which are among the highest achievable in present-day energy systems. At turbine inlet temperatures higher than 650 deg C single heating CO2 cycles exhibit a better efficiency than reheat steam cycles. This may prove of particular interest in connection with high temperature nuclear heat sources. However, the requirement of low temperature cooling water for a good cycle arrangement represents a geographical limitation to the widespread application of CO2 condensation cycles.

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The potential performance of carbon dioxide as working fluid is recognized to be similar to that of steam, which justifies thorough thermodynamic analysis of possible cycles. The substantially better results achievable with CO2 with respect to other gases are due to the real gas behaviour in the vicinity of the Andrews curve. Simple cycles benefit from the reduced compression work, but their efficiency is compromised by significant losses caused by irreversible heat transfer. Their economy, however, is appreciably better than that of perfect gas cycles. More complex cycle arrangements, six of which are proposed and analyzed in detail, reduce heat transfer losses while maintaining the advantage of low compression work and raise cycle efficiency to values attained only by the best steam practice. Some of the cycles presented were conceived to give a good efficiency at moderate pressure which is of particular value in direct-cycle nuclear applications. The favourable influence on heat transfer coefficients of the combined variation with pressure of mechanical, thermal and transport properties, due to real gas effects, is illustrated. Technical aspects as turbo-machines dimensions and heat transfer surfaces needed for regeneration are also considered. Cooling water requirements are found to be not much more stringent than in steam stations.

The potential merits of cyclic polymethylsiloxanes, particularly those conventionally denominated D4 and D5, as working fluids for space power cycles are discussed. The attractive technical characteristics of these substances which are fully nontoxic, moderately flammable, and stable at high temperature are presented. Some experimental results on vapor pressure and on thermal stability are reported. A maximum operating temperature of about 400°C appears achievable. A comprehensive thermodynamic analysis comparing siloxanes with other classes of high temperature fluids is performed. The peculiar characters of siloxane cycles are found to be: a good overall efficiency achieved through a massive regeneration, a moderate expansion work, and an abundant volume flow at turbine exhaust. A number of two-stage turbines for two power levels (i.e., 30 and 5 kW) were designed using an appropriate optimization program. The resulting main features of such expanders were a satisfactory efficiency, a low rotating and peripheral speed, and a comparatively large wheel diameter. These characteristics seem of particular interest for low capacity systems where, with other fluids, turbines tend to be impractically small and fast rotating and where a high level of regeneration becomes more acceptable. In considering for the sake of comparison the thermodynamic performance of many classes of organic fluids, it becomes apparent that the full potential of organic power cycles in view of the variety of future needs has not yet been thoroughly investigated.

The possibility of performing a liquid phase compression in closed cycle gas turbine through the use of particular working fluids is discussed. From the results of calculations carried out for different fluids there is evidence that efficiency of the resulting cycle is considerably higher than that of regenerative Brayton cycles and comparable with that of regenerative Rankine cycles. The working fluid selection is recognized as the major problem in view of practical applications. Available data strongly support the conclusion that fluids meeting the needed requirements, at least for moderate temperature operation, can be found. Nuclear power stations appear to be one of the most promising fields of application of the liquid phase compression cycle.