It has previously been reported that epitaxial growth of ZnO can be obtained at low temperatures by atomic layer deposition (ALD) onto a GaN (0001-Ga) surface, corresponding to a~2.3% compressive lattice mismatch of the deposited ZnO. The question addressed here is the atomic ordering of deposited ZnO as a function of the lattice mismatch between ZnO and several single-crystal seeding surfaces. We have deposited ZnO using ALD onto either the (111) cubic or (0001) hexagonal surfaces of a set of available single-crystal substrates (GaAs, InP, GaN, SiC), for which the lattice mismatch varies over a wide range of values, positive and negative. It is found that deposition onto surfaces with very high extensive lattice mismatch (GaAs, InP) leads to polycrystalline ZnO, similar to the configuration obtained on an amorphous SiO 2 surface. In contrast, ZnO ALD deposition onto both 2H-GaN (0001-Ga) and 4H-SiC (0001-Si) surfaces with lower and compressive mismatch leads to epitaxial ordering over the whole substrate temperature range of 180-250 • C.
We used a sol–gel spin coating technique to synthesize nanocomposite thin films based on zinc oxide (ZnO) loaded with silver nanoparticles (NPs). We tested these ZnO/Ag NP photocatalysts, with a thickness of about 100 nm, for the photodegradation of the indigo carmine dye solution. The study focused on the effects of Ag NPs on the ZnO matrix as well as the impact of their concentration on the photocatalytic performance of the nanocomposite. The study also highlighted the high stability of the photocatalytic performance of these nanocomposites. This work is a contribution in the search for non-toxic thin film photocatalysts that is usable under solar radiation for the treatment of contaminated wastewater. Innovation in the field of heterogeneous photocatalysis requires the use of solar resource with efficient results in terms of photocatalytic performance.
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