This review goal is to reflect on the challenges and prospects for water quality in the face of the pandemic caused by the new SARS-CoV-2 coronavirus (COVID-19). Based on the information available so far, the detection of SARS-CoV-2 RNA in wastewater has raised interest in using it as an early warning method, to detect the resurgence of infections and to report the risk associated with contracting SARS-CoV-2 in contact with untreated water or inadequately treated wastewater is discharged. The wastewater-based epidemiological approach can be used as an early indicator of infection within a specific population. On the other hand, it is necessary to collect information from the managers of drinking water supply companies and professionals who are related to water quality, to know SARS-CoV-2 data and information, and its influence on drinking water quality. The basic purpose of this review article is to try to provide a valuable and quick reference guide to COVID-19. Important topics were discussed, such as detection of SARS-CoV-2 in wastewater in various parts of the world; wastewater screening to monitor COVID-19; persistence of SARS-CoV-2 in aquatic systems; the presence of SARS-CoV-2 in drinking water; clean water as a mechanism to deal with the COVID-19 pandemic; chlorine as a disinfectant to eliminate SARS-CoV-2 and damage to ecosystems by the use of chlorine. Currently does not exist extensive literature on the effectiveness of water and wastewater treatment processes that ensure the correct elimination of SARS-CoV-2. Excessive use of disinfectants such as chlorine is causing effects on the environment. This document highlights the need for further research to establish the behavior of the SARS-CoV-2 virus in aquatic systems. This study presents an early overview of the observed and potential impacts of COVID-19 on the environment.
Due to the outbreak of the novel coronavirus disease there is a need for public water supply of the highest quality. Adequate levels of chlorine allow immediate elimination of harmful bacteria and viruses and provide a protective residual throughout the drinking water distribution network (DWDN). Therefore, a residual chlorine decay model was developed to predict chlorine levels in a real drinking water distribution network. The model allowed determining human exposure to drinking water with a deficit of residual chlorine, considering that it is currently necessary for the population to have clean water to combat coronavirus Covid 19. The chlorine bulk decay rates (kb) and the reaction constant of chlorine with the pipe wall (kw) were experimentally determined. Average kb and kw values of 3.7 d− 1 and 0.066 m d− 1 were obtained, respectively. The values of kb and kw were used in EPANET to simulate the chlorine concentrations in a DWDN. The residual chlorine concentrations simulated by the properly calibrated and validated model were notably close to the actual concentrations measured at different points of the DWDN. The results showed that maintaining a chlorine concentration of 0.87 mg L− 1 in the distribution tank, the residual chlorine values in the nodes complied with the Ecuadorian standard (0.3 mg L− 1); meanwhile, about 45% of the nodes did not comply with what is recommended by the WHO as a mechanism to combat the current pandemic (0.5 mg L− 1). This study demonstrated that residual chlorine modeling is a valuable tool for monitoring water quality in the distribution network, allowing to control residual chlorine levels in this pandemic season.
The bulk chlorine decay rate in drinking water supply systems depend on many factors, including temperature. In this document, the method to determine the order of reaction of chlorine with water is reported, as well as the method to estimate Kb (Bulk reaction rate constant). Experiments were carried out to determine the bulk chlorine decay, for which a set of water samples to determine the free residual chlorine every hour were analyzed. Chlorine concentrations were graphed against time and adjusted appropriately to the developed model. The experimental results showed that the average value of the mass decomposition rate was 0.15 h −1 . It was shown that temperature affects the variation of the reaction rate of chlorine with water, Kb increases as temperature increases. In this manuscript it is reported: The method that allows determining the reaction kinetic order of chlorine with drinking water. The method that can help residual chlorine modelers in the correct definition of the bulk reaction rate constant. The effectiveness of the method for evaluating the decomposition of residual chlorine in drinking water distribution networks as a function of temperature.
This document presents the physical-chemical parameters with the objective of evaluating and analyzing the drinking water quality in the Azogues city applying the water quality index (WQI) and to research the water stability in the distribution network using corrosion indexes. Thirty samples were collected monthly for six months throughout the drinking water distribution network; turbidity, temperature, electric conductivity, pH, total dissolved solids, total hardness, calcium, magnesium, alkalinity, chlorides, nitrates, sulfates and phosphates were determined; the physical-chemical parameters were measured using standard methods. The processed data revealed that the average values of LSI, RSI and PSI were 0.5 (±0.34), 6.76 (±0.6), 6.50 (±0.99) respectively. The WQI calculation indicated that 100% of the samples are considered excellent quality water. According to the Langelier, Ryznar and Pukorius indexes showed that drinking water in Azogues is corrosive. The quality of drinking water according to the WQI is in a good and excellent category.
Petroleum-derived products, such as lubricant oils, are non-renewable resources that, after use, must be collected and processed properly to avoid negative environmental impacts. A circular economy of used oils requires the re-refining and reuse of the same. Similar to most countries in Latin America, the management of used oils in Ecuador is still incipient and few cities collect and treat this material properly. In Cuenca, the ETAPA company collects ~1344 t/year of used oils, which are subjected to pretreatment operations prior to their use as fuel in a cement factory. However, combustion generates polluting gases and disallows the adding of value to the used oils. The lack of studies on the characterization and methods utilized for recovering used oils under the conditions found in medium-size Latin-American cities (e.g., Cuenca), alongside a lack of government policies, have hindered the adoption of re-refining operations. The objective of this work is to characterize the used lubricant oils in Cuenca, to compare them with the properties of used oils from other countries, and to suggest some re-refining technologies for oils with similar properties. Used oil samples were collected from mechanic shops and car-lubricating shops for characterization. Its physicochemical properties and metal contents are comparable to the used oils in other countries globally. Specifically, the flash point, kinematic viscosity, TBN, and concentrations of Zn, Cd, and Mg are similar to the properties of used oils in Iraq, Egypt, and the United Arab Emirates. Based on these results, the best re-refining option for used oils in Cuenca is extraction with solvents in which sedimentation and dehydration (already conducted in Cuenca) is followed by a solvent reaction process, a vacuum distillation process, a finishing process with bentonite, and a final filtration step.
The quality of drinking water flowing in a distribution network can possess corrosive characteristics that may cause the material degradation of pipes and accessories. This problem can result in reduction of the service life of pipes and create a major public health problem. The agreement between the physical-chemical water quality analysis and national standards are not enough to confirm the balance of the water quality in terms of corrosion. In order to predict pipe corrosion in water distribution system networks, the corrosive trend was evaluated using the Langelier (LSI), Ryznar (RSI), and Larson-Skold (LRI) indexes based on measurements of pH, temperature, total dissolved solids, alkalinity, calcium hardness, sulfate and chloride. This study was setup with 180 samples collected in six zones of the distribution network, from July to December of 2017, according to the standard methods for the analysis of drinking water. The results indicate a variation of the LSI from -1.22 to -1.68; RSI from 9.75 to 10.52 and LRI from 0.46 to 0.77. A linear model was fitted for each index to predict the corrosion with the water quality conditions of this study case. Therefore, the drinking water of the city of Azogues, Ecuador has a corrosive tendency from significant to severe. Corrosion indices were calculated to provide useful information on the water's corrosiveness. These results indicate the need to constantly monitor the corrosion rate in the distribution network and conduct a laboratory study to adjust effective parameters such as pH, in order to control corrosion.
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