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Carbon-13 chemical shifts of 8 chromones and 35 isoflavones variously substituted by hydroxy-, acetoxy-, and methoxy-groups are assigned. The applicability of chemical shift increments reflecting inductive and resonance effects is discussed. Some general relations between substitution patterns and carbon shielding useful for the identification of naturally occurring isoflavones are outlined. Typical C—H couplings of chromone and phenyl carbons are analyzed for a 4′,6,7-trisubstituted derivative.

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