Films based on poly(vinylidene fluoride) (PVDF) blended with ionic liquids (ILs) comprising different cations and anions were developed to investigate the IL influence on the resulting PVDF crystalline phase. Blends with 25 wt % IL content were produced by solvent casting followed by solvent evaporation at 210 °C in an air oven. Five different ILs containing the same cation 1-ethyl-3-methylimidazolium [Emim] and five ILs containing the same anion bis(trifluoromethylsulfonyl)imide [TFSI] were selected. The formation of the different phases and the resulting thermal and dynamic mechanical properties were studied by Fourier transform infrared spectroscopy, differential scanning calorimetry, and dynamic mechanical analysis. The incorporation of [Emim]-based ILs successfully directs the PVDF crystallization from the nonpolar α-phase toward the electroactive and highly polar β-phase. On the contrary, blends containing [TFSI] as a
Over the years, our oceans have witnessed an enormous accumulation of marine plastic waste resulting from ocean-related economic activities. As plastic pollution adversely affects marine wildlife and habitat, our society requires urgent solutions to address this increasingly alarming dilemma. Here, we turn our attention to circular economy principles to reduce the amount of nonbiodegradable petroleum-based marine litter. We consider a production process based on 3D printing to fabricate products for the marine industry, which uses marine plastic waste as a source material. Additionally, the suitability of virgin bio-based polyamide (bio-PA), polylactic acid (PLA), and polyhydroxybutyrate (PHB) is explored. PHB is selected due to its extraordinary rapid biodegradation in aquatic environments. To quantify the environmental impacts of the proposed processes, a cradle-to-grave life cycle assessment (LCA) is applied according to ISO 14040:2006 and ISO 14044:2006 standards. Different endof-life alternatives are proposed, including landfill deposition, thermal degradation, and composting. LCA results reveal that the use of marine plastic waste is environmentally preferred in comparison with bio-PA, PLA, and PHB. Specifically, the global warming indicator, considered a prime driver toward sustainability, shows a 3.7-fold decrease in comparison with bio-PA. Importantly, the environmental impacts of PHB production through crude glycerol fermentation are quantified for the first time.Regarding the end-of-life options with a composting scenario, PLA and PHB are preferred as they yield biogenic carbon dioxide (CO 2 ), which can be used as a renewable energy source.
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