Ambient noise tomography has proven to be effective in resolving shallow earth structure. We applied ambient noise tomography on a dense seismic array in Long Beach, California. The array was composed of more than 5200 stations with an average spacing close to 100 m. Three weeks of passive ambient noise were crosscorrelated between each station pair, which resulted in more than 13.5 million crosscorrelations within the area. Clear fundamental-mode Rayleigh waves were observed between 0.5 and 4 Hz, which were most sensitive to structure above 1-km depth. For each station pair, we applied frequency-time analysis to determine the phase traveltime dispersion, and, for each frequency, we applied eikonal tomography to determine the Rayleigh wave phase velocity map. The eikonal tomography accounted for ray bending by tracking the wavefront and allowed uncertainties to be estimated through statistical analysis. The compilation of phase velocity maps was then used to invert for 3D shear velocity structure. The inverted model showed clear correlation with the known geologic features such as the shallow south-north velocity dichotomy and a deeper fast anomaly associated with the NewportInglewood fault zone. Our results can potentially be used to complement traditional active source studies.

Polypropylene-based products are commonly used for food preparation and storage, but their capacity to release microplastics is poorly understood. We investigated the potential exposure of infants to microplastics from consuming formula prepared in polypropylene infant feeding bottles (PP-IFBs). Here, we show that PP-IFBs release microplastics with values as high as 16,200,000 particles/L. Scenario studies showed that PP-IFB sterilisation and exposure to high temperature water significantly increase microplastic release. A 21-day test of PP-IFBs showed periodic fluctuations in microplastic release. To estimate the potential global exposure to infants up to 12 months old, we surveyed 48 regions finding values ranging from 14,600 to 4,550,000 particles per capita per day, depending on the region. We demonstrate that infant exposure to microplastics is higher than previously recognized due to the prevalence of polypropylene-based products in formula preparation, highlighting an urgent need to assess whether MPs exposure at these levels pose a risk to infant health. A formula preparation scheme that reduces the exposure of infants to microplastics is suggested.

finite-difference (FD) synthetics, which fill the gap between fast 1-D analytic synthetics and time-consuming full 3-D synthetics in our ability to model seismograms, have been used in many studies. We address several issues involving 2-D FD methods in generating global synthetic seismograms. These include: (1) interfacing point source excitation for earthquakes with 2-D FD methods; (2) out-of-plane spreading corrections and (3) reducing the spherical Earth to the flattened models. The first issue is tackled using two methods, a 'transparent source box' approach and a moment tensor excitation approach, where each has its own advantages. Moreover, our 'source box' excitation does not have the late-time drift problem that occurred in previous studies. The out-of-plane geometric spreading correction is accounted for by estimating the ray parameter and applying a post-simulation filter to 2-D synthetics. Finally, parameters of the Earth-flattening transformation are discussed and validated. The effectiveness of this method is demonstrated by comparing our synthetics with frequency-wavenumber summation, normal-mode and 3-D spectral-element synthetics.

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S U M M A R YWe show that higher modes are an important component of high-frequency Rayleigh waves in the cross-correlations over sedimentary basins. The particle motions provide a good test for distinguishing and separating the fundamental from the first higher mode, with the fundamental mode having retrograde and the first higher mode having prograde motion in the 1-10 s period of interest. The basement depth controls the cut-off period of the first higher mode, which coincides with a rapid increase (over period) in the particle-motion ellipticity or H/V ratio of the fundamental mode. The strong higher mode we observed is not only due to the low-velocity sedimentary layer but also due to the noise sources with significant radial component such as the basin edge scattering. It is important to correctly identify the mode order when inverting the dispersion curves because misidentifying the higher mode as fundamental will lead to an anomalous high V SV velocity.

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S U M M A R YWe develop and study an adjoint-based inversion method for the simultaneous recovery of initial temperature conditions and viscosity parameters in time-dependent mantle convection from the current mantle temperature and historic plate motion. Based on a realistic rheological model with temperature-dependent and strain-rate-dependent viscosity, we formulate the inversion as a PDE-constrained optimization problem. The objective functional includes the misfit of surface velocity (plate motion) history, the misfit of the current mantle temperature, and a regularization for the uncertain initial condition. The gradient of this functional with respect to the initial temperature and the uncertain viscosity parameters is computed by solving the adjoint of the mantle convection equations. This gradient is used in a preconditioned quasi-Newton minimization algorithm. We study the prospects and limitations of the inversion, as well as the computational performance of the method using two synthetic problems, a sinking cylinder and a realistic subduction model. The subduction model is characterized by the migration of a ridge toward a trench whereby both plate motions and subduction evolve. The results demonstrate: (1) for known viscosity parameters, the initial temperature can be well recovered, as in previous initial condition-only inversions where the effective viscosity was given; (2) for known initial temperature, viscosity parameters can be recovered accurately, despite the existence of trade-offs due to ill-conditioning; (3) for the joint inversion of initial condition and viscosity parameters, initial condition and effective viscosity can be reasonably recovered, but the high dimension of the parameter space and the resulting ill-posedness may limit recovery of viscosity parameters.

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