Tin‐based perovskites with excellent optoelectronic properties and suitable band gaps are promising candidates for the preparation of efficient lead‐free perovskite solar cells (PSCs). However, it is challenging to prepare highly stable and efficient tin‐based PSCs because Sn2+ in perovskites can be easily oxidized to Sn4+ upon air exposure. Here we report the fabrication of air‐stable FASnI3 solar cells by introducing hydroxybenzene sulfonic acid or its salt as an antioxidant additive into the perovskite precursor solution along with excess SnCl2. The interaction between the sulfonate group and the Sn2+ ion enables the in situ encapsulation of the perovskite grains with a SnCl2–additive complex layer, which results in greatly enhanced oxidation stability of the perovskite film. The corresponding PSCs are able to maintain 80 % of the efficiency over 500 h upon air exposure without encapsulation, which is over ten times longer than the best result reported previously. Our results suggest a possible strategy for the future design of efficient and stable tin‐based PSCs.
Passivating surface and bulk defects of perovskite films has been proven to be an effective way to minimize nonradiative recombination losses in perovskite solar cells (PVSCs). The lattice interference and perturbation of atomic periodicity at the perovskite surfaces often significantly affect the material properties and device efficiencies. By tailoring the terminal groups on the perovskite surface and modifying the surface chemical environment, the defects can be reduced to enhance the photovoltaic performance and stability of derived PVSCs. Here, we report a rationally designed bifunctional molecule, piperazinium iodide (PI), containing both R 2 NH and R 2 NH 2 + groups on the same six-membered ring, behaving both as an electron donor and an electron acceptor to react with different surface-terminating ends on perovskite films. The resulting perovskite films after defect passivation show released surface residual stress, suppressed nonradiative recombination loss, and more n-type characteristics for sufficient energy transfer. Consequently, charge recombination is significantly suppressed to result in a high open-circuit voltage (V OC ) of 1.17 V and a reduced V OC loss of 0.33 V. A very high power conversion efficiency (PCE) of 23.37% (with 22.75% certified) could be achieved, which is the highest value reported for inverted PVSCs. Our work reveals a very effective way of using rationally designed bifunctional molecules to simultaneously enhance the device performance and stability.
2D perovskites have emerged as one of the most promising photovoltaic materials owing to their excellent stability compared with their 3D counterparts. However, in typical 2D perovskites, the highly conductive inorganic layers are isolated by large organic cations leading to quantum confinement and thus inferior electrical conductivity across layers. To address this issue, the large organic cations are replaced with small propane-1,3-diammonium (PDA) cations to reduce distance between the inorganic perovskite layers. As shown by optical characterizations, quantum confinement is no longer dominating in the PDA-based 2D perovskites. This leads to considerable enhancement of charge transport as confirmed with electrochemical impedance spectroscopy, time-resolved photoluminescence, and mobility measurements. The improved electric properties of the interlayer-engineered 2D perovskites yield a power conversion efficiency of 13.0%. Furthermore, environmental stabilities of the PDA-based 2D perovskites are improved. PDA-based 2D perovskite solar cells (PSCs) with encapsulation can retain over 90% of their efficiency upon storage for over 1000 h, and PSCs without encapsulation can maintain their initial efficiency at 70 °C for over 100 h, which exhibit promising stabilities. These results reveal excellent optoelectronic properties and intrinsic stabilities of the layered perovskites with reduced interlayer distance.
Maintaining
the stability of tin halide perovskites is a major
challenge in developing lead-free perovskite solar cells (PSCs). Adding
extra SnX2 (X = F, Cl, or Br) in the precursor solution
to inhibit Sn2+ oxidation is an essential strategy to improve
device efficiency and stability. However, SnX2 on the surface
of perovskite grains tends to prohibit charge transfer across perovskite
films. Here, we report a coadditive engineering approach by introducing
antioxidant gallic acid (GA) together with SnCl2 to improve
the performance of tin-based PSCs. The SnCl2–GA
complex can not only protect the perovskite grains but also more effectively
conduct electrons across it, leading to highly stable and efficient
PSCs. The unencapsulated devices can maintain ∼80% of their
initial efficiency after 1000 h of storage in ambient air with a relative
humidity of 20%, which is the best air stability achieved in tin-based
PSCs to date.
α‐Formamidinium lead triiodide (α‐FAPbI3) represents the state‐of‐the‐art for perovskite solar cells (PSCs) but experiences intrinsic thermally induced tensile strain due to a higher phase‐converting temperature, which is a critical instability factor. An in situ crosslinking‐enabled strain‐regulating crystallization (CSRC) method with trimethylolpropane triacrylate (TMTA) is introduced to precisely regulate the top section of perovskite film where the largest lattice distortion occurs. In CSRC, crosslinking provides in situ perovskite thermal‐expansion confinement and strain regulation during the annealing crystallization process, which is proven to be much more effective than the conventional strain‐compensation (post‐treatment) method. Moreover, CSRC with TMTA successfully achieves multifunctionality simultaneously: the regulation of tensile strain, perovskite defects passivation with an enhanced open‐circuit voltage (VOC = 50 mV), and enlarged perovskite grain size. The CSRC approach gives significantly enhanced power conversion efficiency (PCE) of 22.39% in α‐FAPbI3‐based PSC versus 20.29% in the control case. More importantly, the control PSCs’ instability factor—residual tensile strain—is regulated into compression strain in the CSRC perovskite film through TMTA crosslinking, resulting in not only the best PCE but also outstanding device stability in both long‐term storage (over 4000 h with 95% of initial PCE) and light soaking (1248 h with 80% of initial PCE) conditions.
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