Nafion membranes are still the dominating material used in the polymer electrolyte membrane (PEM) technologies. They are widely used in several applications thanks to their excellent properties: high proton conductivity and high chemical stability in both oxidation and reduction environment. However, they have several technical challenges: reactants permeability, which results in reduced performance, dependence on water content to perform preventing the operation at higher temperatures or low humidity levels, and chemical degradation. This paper reviews novel composite membranes that have been developed for PEM applications, including direct methanol fuel cells (DMFCs), hydrogen PEM fuel cells (PEMFCs), and water electrolysers (PEMWEs), aiming at overcoming the drawbacks of the commercial Nafion membranes. It provides a broad overview of the Nafion-based membranes, with organic and inorganic fillers, and non-fluorinated membranes available in the literature for which various main properties (proton conductivity, crossover, maximum power density, and thermal stability) are reported. The studies on composite membranes demonstrate that they are suitable for PEM applications and can potentially compete with Nafion membranes in terms of performance and lifetime.
In this paper we discuss a computational method focused on the prediction of unsteady aerodynamics, adequate for industrial turbomachinery. Here we focus on a single rotor device selected from a new family of large tunnel ventilation axial flow fans. The flow field in the fan was simulated using the open source code OPENFOAM, with a large-eddy simulation (LES) approach. The sub-grid scale (SGS) closure relied on a one-equation model, that requires us to solve a differential transport equation for the modeled SGS turbulent kinetic energy. The use of such closure was here considered as a remedial strategy in LES of high-Reynolds industrial flows, being able to tackle the otherwise insufficient resolution of turbulence spectrum. The results show that LES of the fan allows to predict the pressure rise capability of the fan and to reproduce the most relevant flow features, such as three-dimensional separation and secondary flows
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