The 660-km seismic discontinuity, which is a significant structure in the Earth’s mantle, is generally interpreted as the post-spinel transition, as indicated by the decomposition of ringwoodite to bridgmanite + ferropericlase. All precise high-pressure and high-temperature experiments nevertheless report 0.5–2 GPa lower transition pressures than those expected at the discontinuity depth (i.e. 23.4 GPa). These results are inconsistent with the post-spinel transition hypothesis and, therefore, do not support widely accepted models of mantle composition such as the pyrolite and CI chondrite models. Here, we present new experimental data showing post-spinel transition pressures in complete agreement with the 660-km discontinuity depth obtained by high-resolution in situ X-ray diffraction in a large-volume high-pressure apparatus with a tightly controlled sample pressure. These data affirm the applicability of the prevailing mantle models. We infer that the apparently lower pressures reported by previous studies are experimental artefacts due to the pressure drop upon heating. The present results indicate the necessity of reinvestigating the position of mantle mineral phase boundaries previously obtained by in situ X-ray diffraction in high-pressure–temperature apparatuses.
High‐temperature ionic conductivity in olivine single crystals has been measured in the [100], [010], and [001] crystallographic orientations as a function of pressure from 2 to 10 GPa, temperature from 1450 to 2180 K, and H2O content from 20 to 580 wt. ppm using multianvil presses with in situ impedance analyses. The experimental results yield an activation energy, activation volume, and H2O content exponent of 250–405 kJ/mol, 3.2–5.3 cm3/mol, and 1.3 ± 0.2, respectively, for the high‐temperature ionic conduction regime. Olivine ionic conductivity has negative pressure and positive temperature dependences and is significantly enhanced by H2O incorporation. The [001] direction is more conductive than the [100] and [010] directions. The H2O‐enhanced ionic conductivity may contribute significantly to the electrical conductivity profile in the asthenosphere, especially in the regions under relatively high‐temperature and low‐pressure conditions.
The Earth's mantle is characterised by a sharp seismic discontinuity at a depth of 660-km that can provide insights into deep mantle processes. The discontinuity occurs over only 2km -or a pressure difference of 0.1 GPa -and is thought to result from the post-spinel transition, that is, the decomposition of the mineral ringwoodite to bridgmanite plus ferropericlase. Existing high-pressure-temperature experiments have lacked the pressure control required to test whether such sharpness is the result of isochemical phase relations or chemically distinct upper and lower mantle domains. Here, we obtain the isothermal pressure interval of the Mg-Fe binary post-spinel transition by applying advanced multianvil techniques with in situ X-ray diffraction with help of Mg-Fe partition experiments. It is demonstrated that the interval at mantle compositions and temperatures is only 0.01 GPa, corresponding to 250 m. This interval is indistinguishable from zero at seismic frequencies. These results can explain the discontinuity sharpness and provide new support for whole mantle convection in a chemically homogeneous mantle. The present work suggests that distribution of adiabatic vertical flows between the upper and lower mantles can be mapped based on discontinuity sharpness.
Main:The 660-km seismic discontinuity (D660) is the boundary between the upper and lower mantles. Seismological studies based on short-period P-wave reflections (Pʹ660Pʹ-PʹPʹ) have demonstrated that D660 is extremely sharp and less than 2 km thick 1 , which is in striking contrast to the 7-km-thick 410-km discontinuity 1 . Understanding the nature of D660 from a perspective of mineral physics provides important clues to open questions about the structure and dynamic processes in the Earth's mantle, such as slab subduction and upwelling of hot plume.Geochemical studies suggest that the Earth's upper mantle consists of ca. 60% atom-
We have generated over 40 GPa pressures, namely, 43 and 44 GPa, at ambient temperature and 2000 K, respectively, using Kawai-type multi-anvil presses (KMAP) with tungsten carbide anvils for the first time. These high-pressure generations were achieved by combining the following pressure-generation techniques: (1) precisely aligned guide block systems, (2) high hardness of tungsten carbide, (3) tapering of second-stage anvil faces, (4) materials with high bulk modulus in a high-pressure cell, and (5)
In
this work, we report an experimental observation of a new CaCO3 calcite-Vb phase, which occurs as the intermediate between
aragonite and calcite-V at pressures >3.5 GPa and temperatures
>1200
°C, suggesting it can exist in CaCO3-containing rocks
at ∼125–200 km. Calcite-Vb is determined to have the
KClO3-type structure with the monoclinic P21/m space group and lattice parameters
of a = 6.284(5) Å, b = 4.870(3)
Å, c = 3.991(4) Å, β = 107.94(3)°,
and V = 116.19(15) Å3. Possible transformation
mechanisms between calcite-Vb, aragonite, and calcite-V are illustrated.
Chemical reactions and phase stabilities in the Si− Te system at high pressures were explored using in situ angledispersive synchrotron powder diffraction in a large-volume multianvil press together with density functional theory-based calculations. Cubic and rhombohedrally distorted clathrates, with the general formula Te 8 @(Si 38 Te 8 ) and wide compositional range, preceded by a hexagonal phase with the composition Si 0.14 Te, are formed for different mixtures of Si and Te as starting materials. Si 0.14 Te, with the structural formula Te 2 (Te 0.74 Si 0.26 ) 3 (Te 0.94 Si 0.06 ) 3 , is the very first chalcogenide with the Mn 5 Si 3 -type structure. Silicon sesquitelluride α-Si 2 Te 3 decomposes into a mixture of phases that includes the clathrate and hexagonal phases at high pressures and high temperatures. The higher the pressure, the lower the temperature for the two phases to occur. Regardless of the starting compositions, only the clathrate is quenched to atmospheric conditions, while the hexagonal phase amorphizes on decompression. The rhombohedral clathrates Te 8 @(Si 38 Te 8 ) form on quenching of the cubic phases to ambient conditions. There is a high degree of interchangeability of Si and Te not only in the clathrates but also in the Mn 5 Si 3 -type structure. The theoretical calculations of enthalpies indicate that the reported decomposition of α-Si 2 Te 3 is energetically favorable over its transformation to another polymorph of the A 2 X 3 type at extreme conditions.
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