Highlights-Density of liquid Fe-S alloys has been measured under high pressure as a function of temperature by in situ X-ray diffraction in multi-anvil press.-Thermal expansion of liquid Fe-S alloys has been determined up to 7 GPa and 2200 K.-Top-down crystallization is the most likely scenario for Fe-FeS cores of planetesimals and small planets.
Recent studies show that the D′′ layer, just above the Earth's core–mantle boundary, is composed of MgSiO3 post-perovskite and has significant lateral inhomogeneity. Here we consider the D′′ diversity as related to the single-crystal elasticity of the post-perovskite phase. We measure the single-crystal elasticity of the perovskite Pbnm-CaIrO3 and post-perovskite Cmcm-CaIrO3 using inelastic X-ray scattering. These materials are structural analogues to same phases of MgSiO3. Our results show that Cmcm-CaIrO3 is much more elastically anisotropic than Pbnm-CaIrO3, which offers an explanation for the enigmatic seismic wave velocity jump at the D′′ discontinuity. Considering the relation between lattice preferred orientation and seismic anisotropy in the D′′ layer, we suggest that the c axis of post-perovskite MgSiO3 aligns vertically beneath the Circum-Pacific rim, and the b axis vertically beneath the Central Pacific.
The diffuse scattering signal of amorphous or liquid systems contains information on the local atomic structure, and this can be related to the density, compressibility, thermal expansion and other thermo-elastic properties. However, the analysis and full exploitation of the diffuse scattering signal, in particular for systems under extreme conditions of high pressures and temperatures is difficult to handle.Amorpheus is a Python-based software allowing the determination of the structure factor and the radial distribution function of amorphous and liquid systems. Based on previously reported methodologies, Amorpheus stands out for the implementation of automatic algorithms allowing the user to choose the most suitable parameters for the data treatment and making possible the systematic analysis of datasets collected in experiments carried out in Paris-Edinburgh press, multi-anvil apparatus or diamond anvil cell.
The InSight mission to Mars is currently monitoring the seismic activity of the planet. Interpretation of seismological observations in terms of composition and mineralogy requires the knowledge of density and thermo‐elastic properties of constituent materials at pertinent conditions. We thus performed phase equilibria experiments and carried out sound velocity and density measurements on aggregates representative of the Martian mantle over pressures and temperatures directly relevant for Mars’ upper and mid mantle. Our results indicate the stability of magnetite, although in a small amount, in phase assemblages at upper mantle conditions, especially in an oxidized environment. The measured pressure and temperature derivatives of compressional and shear velocities show that the temperature‐induced reduction of seismic wave speeds dominates over pressure‐induced effects at Mars' shallow mantle conditions for the predicted areotherms and, independently from mineralogy, support the presence of a low‐shear‐wave‐velocity layer between 150 and 350 km depth, in agreement with seismic observations.
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