The article describes an easy-to-implement and print-ready composition for inkjet printing of magnetic structures, which can be used for security printing, coding, and marking, magnetic device fabrication or creation of micro-antennas.
The observed downsizing tendency of microelectronic devices leads to a higher demand in new types of miniaturized energy sources. Thin‐film Li‐ion batteries (LiBs) are promising candidates to fulfil this function. New materials and technologies should be investigated for customized production of miniaturized, high‐efficient solid‐state batteries. Herein, inkjet printing technology is considered as a promising one for the fabrication of LiBs. The modification of crystalline lattice of Li‐rich cathode material by aluminium, sodium, and potassium and their influence on power efficiency are studied in detail. Lithium‐manganese‐rich compounds are chosen as the most suitable composition of an active component for LiBs fabrication. The stable aqueous colloidal ink composition is synthesized and its rheological parameters are optimized for inkjet printing in terms of viscosity, surface tension, and contact angle. Protocols for inkjet printing for the fabrication of thin‐film cathodes with the thickness of less than 10 μm are reported. The good correlation of electrochemical properties such as average voltage, capacity, and energy between inkjet printed and conventionally fabricated electrodes confirms the feasibility of the suggested technological approach and selected cathode material composition.
This study addresses the inkjet printing approach for fabrication of cellulose nanocrystalline (CNC) patterns with tunable optical properties varied by the thickness of deposited layers. In particular, forming functional patterns visible only in linearly polarized light is of the primary interest. The possibility of controlling the bright iridescent color response associated with the birefringence in the chiral anisotropic structure of inkjet-printed layers of CNC with sulfo-groups (s-CNC) has been thoroughly investigated. In this connection, we have elaborated an appropriate synthesis sequence for deriving printable inks in the form of sedimentation-stable s-CNC colloids with various concentrations of solid phase and experimentally determined the optimal regimes of their inkjet printing. For this purpose, the rheological parameters and s-CNC particle concentration have also been optimized. The study is accomplished with a comprehensive optical characterization of the deposited s-CNC layers with variable thickness, drying conditions, and the polarization state. The experimental results demonstrate the feasibility of inkjet printing technology to perform the precise fabrication of optically active s-CNC patterns with variable optical properties. These results are particularly relevant for applications requiring special conditions of color demonstration in security printing for such as anticounterfeiting applications, polygraphy decoration printing, and color photo filters.
This study is devoted to the development of photonic patterns based on polystyrene spheres (PSS) incorporated in chitosan hydrogels by inkjet printing. Using this method, high-resolution encrypted images that became visible only in high humidity were obtained. Inks based on PSS with carboxylic groups on the surface were made, and their rheological parameters (viscosity, surface tension, and ζ-potential) were optimized according to the Ohnesorge theory. The obtained value of the ζ-potential indicated the stability of the synthesized colloidal inks. The dependences of the printing parameters on the concentration of ethylene glycol in PSS dispersion, the drop spacing, the shape of the printed pattern, waveform, the temperature of the printing process, and the degree of ordering of the PSS-based photonic crystal were investigated. The scanning electronic microscope (SEM) images confirmed that the optimal self-organization of PSS was achieved at the following values of 0.4% weight fraction (wt%) carboxylic groups, the drop spacing of 50 μm, and the temperature of the printing table of 25 °C. High-resolution microstructures were obtained by drop-on-demand printing with a deposited drophead diameter of 21 μm and an accuracy of ±2 μm on silicon and glass substrates. The deposition of chitosan-based hydrogels on the obtained polystyrene photonic crystals allowed reversibly changing the order of the diffraction lattice of the photonic crystal during the swelling of the hydrogel matrix, which led to a quick optical response in the daylight. The kinetics of the appearance of the optical response of the obtained coating were discussed. The simplicity of production, the speed of image appearance, and the ability to create high-resolution patterns determine the potential applications of the proposed systems as humidity sensors or anticounterfeiting coatings.
A planar memristor was fabricated by a hybrid method combining AFM patterning and inkjet printing.
Rapid detection of bacterial contamination is an essential task in numerous medical and technical processes and one of the most rapidly developing areas of nano-based analytics. Here, we present a simple-to-use and special-equipment-free test-system for bacteria detection based on magnetite nanoparticle arrays. The system is based on peroxide oxidation of chromogenic substrate catalyzed by magnetite nanoparticles, and the process undergoes computer-aided visual analysis. The nanoparticles used had a pristine surface free of adsorbed molecules and demonstrated high catalytic activities up to 6585 U/mg. The catalytic process showed the Michaelis–Menten kinetic with Km valued 1.22 mmol/L and Vmax of 4.39 µmol/s. The nanoparticles synthesized were used for the creation of inkjet printing inks and the design of sensor arrays by soft lithography. The printed sensors require no special equipment for data reading and showed a linear response for the detection of model bacteria in the range of 104–108 colony-forming units (CFU) per milliliter with the detection limit of 3.2 × 103 CFU/mL.
Due to the demand for wearable and implantable microelectronic devices (MED), there is growing interest in the development of thin-film lithium-ion microbatteries (LiBs) with high-energy density. The high cost of production is an issue restraining thin-film LiBs’ wide application. Inkjet printing is a method of applying materials to the substrate surface: ink droplets formed on piezoelectric nozzles fall on the substrate, whereafter evaporation of the solvent thin layer of film is formed. The proposed technology can simplify the production of LiBs for MED and reduce their cost. The present work reports the results of inkjet printing 3D cathode development for LiBs. The 3D printed cathodes were produced using synthesized Li-rich cathode material (Li1.2+xMn0.54Ni0.13Co0.13O2, 0 < x < 0.05) which has a larger capacity (>250 mAh/g) in comparison with the materials used in modern lithium-ion cells. For LiB electrode printing, the non-aqueous solvent-based inks were used. The prepared cathode material was dispersed in N-methyl-2-pyrrolidone. The effect of various additives such as ethylene glycol, diethylene glycol, propylene glycol on the viscosity and stability of the ink was studied. Inkjet printing was performed with the use of a Dimatix Material Printer 2831. Substrate temperature, number of layers and other parameters were varied to determine the optimal printing conditions.
Magnetite (Fe3O4) nanoparticles have found numerous applications due to ease of fabrication, favourable combination of physical and chemical properties, as well as environmental and biological safety. At the same time,...
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