Aglime (agricultural lime), commonly applied to acid soils to increase the soil pH and productivity, may lead to the release of CO2 into the atmosphere or to carbon (C) sequestration, although the processes involved are not fully understood. As large acreages of arable land are limed annually, exploring soil management practices that reduce aglime-induced CO2 emissions from acid soils while maintaining or improving the soil quality is paramount to mitigating the effects of global climate change. This study, therefore, assessed the effects of organic residues and ammonium on CO2 emissions and soil quality indicators in two limed soils. Two contrasting acid soils (Nariva series, Mollic Fluvaquents and Piarco series, Typic Kanhaplaquults) were amended with varying combinations of aglime (0% and 0.2% w/w CaCO3), organic residue (0% and 5% w/w biochar or poultry litter), and NH4-N (0% and 0.02% w/w) and were incubated in 300 mL glass jars for 31 days. The sampling for CO2 was performed on 11 occasions over the course of the incubation, while soil sampling was conducted at the end. The results indicate that aglime application significantly (p < 0.05) increased the cumulative CO2 emissions in all cases except with the addition of poultry litter. Alternatively, ammonium did not regulate the effect of aglime on CO2 emissions, which was l because of the low rate at which it was applied in comparison to aglime. The results also showed that poultry litter significantly (p < 0.05) increased the soil electrical conductivity (EC), available nitrogen (N), and pH, especially in the Piarco soil, while the hardwood biochar had little to no effect on the soil properties. Our findings indicate the potential for utilizing poultry litter to reduce the impact of aglime on CO2 emissions while improving the soil quality. Further studies utilizing 13C to trace aglime CO2 emissions are, however, required to identify the mechanism(s) that contributed to this reduction in the emissions.
In humid tropical environments, where soils are characteristically acidic and low in organic matter, lime and organic residues have been used to improve soil quality. A systematic consideration of their interaction is, therefore, crucial for land-based ecosystem management. A 28-day incubation pot study was carried out to investigate the main and interactive effects of lime and organic residue type (corn stover and vermicompost) on aggregate stability under rapid wetting (WSAr), saturated hydraulic conductivity (Ksat), and soil water repellency (SWR) on three acidic soils with contrasting clay content from Trinidad: Cunupia (Aquic Hapludalfs), Sangre Grande (Fluvaquentic Endoaquepts), and Talparo (Aquertic Eutrudepts). Organic residue had a significant (P≤0.001) increasing effect on WSAr and Ksat for all three soils, this being highest for corn stover and lowest for no residue. Lime and organic residue interactive effects were only significant (P≤0.05) for WSAr in the Cunupia soil, where lime significantly reduced WSAr in the vermicompost and no residue, but not in the corn stover treatment. Soil water repellency increased with clay content and was highest in the lime–corn stover treatment of the Talparo soil. Overall, our results suggest that applying crop residue with lime may help minimise the short-term deleterious effects of lime on the structural and hydraulic properties of humid tropical soils. Nonetheless, future experiments with a wider range of soils and organic residues need to be carried out for a longer term to validate our results.
<p>Formation of mineral-associated organic matter (MAOM) supports accumulation and stabilization of carbon in soil, and thus, is a key factor in the global carbon cycle. Little is known about the interplay of mineral type, land use, and management intensity on the extent of MAOM formation. We addressed this research question by exposing mineral containers with pristine minerals (goethite, as a representative of oxide-type mineral phases, and illite, representing layered aluminosilicate minerals) for five years to ambient soil conditions at 5 cm depth in 150 grassland and 150 forest plots in three regions across Germany. After recovery, the content of organic carbon (OC) of the minerals was determined by dry combustion. Results show that irrespective of land use and management intensity, more OC accumulated on goethite than illite (on average 0.23 and 0.06 mg m<sup>-2</sup> mineral surface, respectively), demonstrating that mineral type was the most crucial factor for MAOM formation. Carbon accumulation was consistently greater in coniferous forests than in deciduous forests and grasslands. Structural equation models revealed that in grasslands, fertilization had contradictory effects on carbon accumulation, with the positive effect being mediated by enhanced plant productivity and the negative effect by reduced plant species richness. Overall, our results suggest that OC stabilization in soil is primarily driven by mineral type, in particular iron and other metal oxides. The mineral-driven MAOM formation is further modified by land use and management intensity.</p>
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