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Purpose -To provide a selective bibliography for graduate students and new faculty members with sources which can help them develop their academic career. Design/methodology/approach -A range of published works, which aim to discuss the main parameters of the volatile corrosion inhibition process. The sources are sorted into sections: transport of the volatile corrosion inhibitor (VCI) to the metallic surface, vapour pressure of a VCI, dependence of vapour pressure upon temperature, effect of pH on VCI behaviour, formation and destruction of adsorbed films, and volatile corrosion inhibitor monitors (VCIM). Findings -Provides information about each source, indicating what can be found there and how the information can help. Recognises the lack of real training of many academics before they are expected to take on teaching/researching duties and finds some texts which help. Research limitations/implications -It is not an exhaustive list and apart from several UK and US books all the rest are EU and US publications which perhaps limits its usefulness elsewhere. Practical implications -A very useful list of the most common compounds used as VCIs is reported. Originality/value -This paper fulfils an identified information/resources need and offers practical help to an individual starting out on and academic career and to professional with some experience on corrosion inhibition.

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BackgroundNeovascularization over dental implants is an imperative requisite to achieve successful osseointegration onto implanted materials. The aim of this study was to investigate the effects on in vitro angiogenesis of anodized 70 nm diameter TiO2 nanotubes (NTs) on Ti6Al4V alloy synthesized and disinfected by means of a novel, facile, antibacterial and cost-effective method using super oxidized water (SOW). We also evaluated the role of the surface roughness and chemical composition of materials of materials on angiogenesis.MethodsThe Ti6Al4V alloy and a commercially pure Ti were anodized using a solution constituted by SOW and fluoride as electrolyte. An acid-etched Ti6Al4V was evaluated to compare the effect of micro-surface roughness. Mirror-polished materials were used as control. Morphology, roughness, chemistry and wettability were assessed by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy, atomic force microscopy, energy dispersive X-ray spectroscopy (EDX) and using a professional digital camera. Bovine coronary artery endothelial cells (BCAECs) were seeded over the experimental surfaces for several incubation times. Cellular adhesion, proliferation and monolayer formation were evaluated by means of SEM. BCAEC viability, actin stress fibers and vinculin cellular organization, as well as the angiogenic receptors vascular endothelial growth factor 2 (VEGFR2) and endothelial nitric oxide synthase (eNOS) were measured using fluorescence microscopy.ResultsThe anodization process significantly increased the roughness, wettability and thickness of the oxidized coating. EDX analysis demonstrated an increased oxygen (O) and decreased carbon (C) content on the NTs of both materials. Endothelial behavior was solidly supported and improved by the NTs (without significant differences between Ti and alloy), showing that endothelial viability, adhesion, proliferation, actin arrangement with vinculin expression and monolayer development were evidently stimulated on the nanostructured surface, also leading to increased activation of VEGFR2 and eNOS on Ti6Al4V-NTs compared to the control Ti6Al4V alloy. Although the rougher alloy promoted BCAECs viability and proliferation, filopodia formation was poor.ConclusionThe in vitro results suggest that 70 nm diameter NTs manufactured by anodization and cleaned using SOW promotes in vitro endothelial activity, which may improve in vivo angiogenesis supporting a faster clinical osseointegration process.