Highly porous hydroxyapatite (Ca 10 (PO 4) 6 (OH) 2 , HAp) catalyst support was prepared through hydrothermal transformation of aragonitic cuttlefish bone (Sepia Officinalis, L., Adriatic Sea) at 200°C, preserving the natural well interconnected porous structure. To deposit the TiO 2 catalyst on the pore walls of the HAp support two methods were used: i) vacuum impregnation of the support with the suspension of a commercial TiO 2 nanopowder in isopropanol and ii) in situ synthesis of TiO 2 on the support by sol-gel technique. XRD analysis and FTIR spectroscopy were used to determine the phase composition of the material. The morphology and microstructure of the composite samples were studied by scanning electron microscopy (SEM). The presence of TiO 2 particles on the HAp surface was determined by SEM/EDX analysis. To determine the specific surface area and pore size, Brunauer-Emmett-Teller (BET) method was used. The results of the BET method showed the increased specific surface area and pore size reduction after impregnation of TiO 2 into the HAp carrier. The photocatalytic activity of HAp/TiO 2 samples was studied in a batch reactor with an annular UV-A lamp using salicylic acid as a model water pollutant. The results indicated the suitability of prepared HAp supported TiO 2 catalysts for photocatalytic applications.
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