This paper reports novel electromechanical behavior for a natural biopolymer film due to the incorporation of a conductive carbon nanotube network. Through simple solution blending and casting, high weight fraction single-walled carbon nanotube-chitosan composite films were fabricated and exhibited electromechanical actuation properties with motion controlled by low alternating voltage stimuli in atmospheric conditions. Of particular interest and importance is that the displacement output imitated perfectly the electrical input signal in terms of frequency (<10 Hz) and waveform. Operational reliability was confirmed by stable vibration testing in air for more than 3000 cycles. Proposed electrothermal mechanism considering the alternating current-induced periodic thermal expansion and contraction of the composite film was discussed. The unique actuation performance of the carbon nanotube-biopolymer composite, coupled with ease of fabrication, low driven voltage, tunable vibration, reliable operation, and good biocompatibility, shows great possibility for implementation of dry actuators in artificial muscle and microsystems for biomimetic applications.
Carbon nanotubes (CNTs) have found many potential applications stemming from their small dimensions and marvellous electronic, mechanical, and thermal properties. One of the barriers for using CNTs as building blocks in nanoelectronics is the high contact resistance. This paper reviews recent progress on the research of contact resistance of CNTs. It starts with a preview of two basic contact configurations, i.e., side contact and end contact, and measurements of contact resistance. The formation of Schottky barrier on a typical metal-semiconductor contact is then presented, aiming at looking for ways to reduce contact resistance from a theoretical point of view. The current techniques for improving CNT contact resistance are classified and summarized as well. The principles and applicabilities of these techniques are compared and discussed. A deep understanding of the forming mechanisms and improvement methods of contact resistance is critical in order to bring CNT-based devices from laboratory to the real-world technology.
In this review, we first briefly recapitulate the orientation characteristics of liquid crystalline carbon nanotubes (CNTs), emphasizing their inherent properties.
Here, we explore the liquid crystalline behavior of carbon nanotubes (CNTs) through two types of commonly physical parameters (the Frank elastic constants k ii (i = 1, 2, 3) in the liquid crystal field that typically describe the nature of molecular orientation, and the Young's modulus E that characterizes the peculiar mechanical properties of CNTs). Droplets of aqueous multiwall carbon nanotube (MWNT) suspensions are evaporated on silica wafer at room temperature in air and the resultant deposits exhibit the hallmark property of liquid crystalline formation, birefringence. And scanning electron microscopic (SEM) characterization further presents the concentric bending arrangement of MWNTs along the circumference at the edge. Then in analogy with liquid crystals, based upon the restraint of circular boundary as in the model of droplets, the CNTs' Frank elasticity is introduced and expresses the relationship with E, showing the dependence of nanotube rigidity and dimensions. By comparing the values of plane parameters k 11 and k 33 , defective properties about CNT-assemblies are provided, with Frank elastic constant anisotropy (k 11 ? k 33 ) contributing to their various distortion structures in the central core of the defects.
We study the dispersion and stability of carbon nanotube (CNT) suspensions under the electrostatic interactions. The potential energies of van der Waals (vdW) attractions between the CNT themselves are obtained on the continuum Lennard-Jones (LJ) model. The potential energies of electrostatic repulsions are based upon the Yukawa-segment model. We explore the overall interactions mediated by the vdW force and the electrostatic force between two identical, parallel CNTs. Consequently, we preliminarily confirm the accuracy and reliability of the electrostatic model.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.