The various studies that consider the life cycle environmental impacts of lithium-ion traction batteries report widely different results. This article evaluates the inventory data and results to identify the key assumptions and differences in the studies. To aid the identification, we compile the reported life cycle greenhouse gas emissions of batteries. The studies find production-related emissions in the range of 38-356 kg CO2-eq/kWh. One of the main sources of the large variations stems from differing assumptions regarding direct energy demand associated with cell manufacture and pack assembly. Further differences are due to assumptions regarding the amount of cell materials and other battery components. The indirect emissions associated with the use phase depend on the conversion losses in the battery, the energy required to transport the weight of the battery, and the carbon intensity of the electricity. Of the reviewed studies assessing the use phase, all estimate energy use associated with conversion losses while only one considers the mass-induced energy requirement. Although there are several industrial end-oflife treatment alternatives for lithium-ion batteries, very few studies consider this life cycle stage. Studies using the "recycled content" approach report emissions in the range of 3.6-27 kg CO2-eq/kWh battery, while studies using the "end-of-life" approach report emission reductions in the range of 16-32 kg CO2eq/kWh battery. The uncertainty associated with the end-of-life results is high as the data availability on industrial process is limited. Based on our findings, we discuss how the life emissions of lithium-ion traction batteries may be reduced.
Electric vehicles (EVs) powered by lithium ion batteries (LIBs) or proton exchange membrane hydrogen fuel cells (PEMFCs) offer important potential climate change mitigation effects when combined with clean energy sources. The development of novel nanomaterials may bring about the next wave of technical improvements for LIBs and PEMFCs. If the next generation of EVs is to lead to not only reduced emissions during use but also environmentally sustainable production chains, the research on nanomaterials for LIBs and PEMFCs should be guided by a lifecycle perspective. In this Review, we describe an environmental lifecycle screening framework tailored to assess nanomaterials for electromobility. By applying this framework, we offer an early evaluation of the most promising nanomaterials for LIBs and PEMFCs and their potential contributions to the environmental sustainability of EV lifecycles. Potential environmental trade-offs and gaps in nanomaterials research are identified to provide guidance for future nanomaterial developments for electromobility.
Keywords:Carbon capture and utilisation CO 2 economy CO 2 -based polyols CO 2 emissions reduction Pedigree analysis A B S T R A C T CO 2 utilisation is gaining interest as a potential element towards a sustainable economy. CO 2 can be used as feedstock in the synthesis of fuels, chemicals and polymers. This study presents a prospective assessment of carbon capture from a hydrogen unit at a refinery, where the CO 2 is either stored, or partly stored and partly utilised for polyols production. A methodology integrating technical, economic and environmental models with uncertainty analysis is used to assess the performance of carbon capture and storage or utilisation at the refinery.Results show that only 10% of the CO 2 captured from an industrial hydrogen unit can be utilised in a commercial-scale polyol plant. This option has limited potential for large scale CO 2 mitigation from industrial sources. However, CO 2 capture from a hydrogen unit and its utilisation for the synthesis of polyols provides an interesting alternative from an economic perspective. The costs of CO 2 -based polyol are estimated at 1200 €/t polyol, 16% lower than those of conventional polyol. Furthermore, the costs of storing the remaining CO 2 are offset by the benefits of cheaper polyol production. Therefore, the combination of CO 2 capture and partial utilisation provides an improved business case over capture and storage alone. The environmental assessment shows that the climate change potential of this CO 2 utilisation system is 23% lower compared to a reference case in which no CO 2 is captured at the refinery. Five other environmental impact categories included in this study present slightly better performance for the utilisation case than for the reference case.
Summary While life cycle assessment (LCA) is a tool often used to evaluate the environmental impacts of products and technologies, the amount of data required to perform such studies make the evaluation of emerging technologies using the conventional LCA approach challenging. The development paradox is such that the inputs from a comprehensive environmental assessment has the greatest effect early in the development phase, and yet the data required to perform such an assessment are generally lacking until it is too late. Previous attempts to formalize strategies for performing streamlined or screening LCAs were made in the late 1990s and early 2000s, mostly to rapidly compare the environmental performance of product design candidates. These strategies lack the transparency and consistency required for the environmental screening of large numbers of early‐development candidates, for which data are even sparser. We propose the Lifecycle Screening of Emerging Technologies method (LiSET). LiSET is an adaptable screening‐to‐LCA method that uses the available data to systematically and transparently evaluate the environmental performance of technologies at low readiness levels. Iterations follow technological development and allow a progression to a full LCA if desired. In early iterations, LiSET presents results in a matrix structure combined with a “traffic light” color grading system. This format inherently communicates the high uncertainty of analysis at this stage and presents numerous environmental aspects assessed. LiSET takes advantage of a decomposition analysis and data not traditionally used in LCAs to gain insight to the life cycle impacts and ensure that the most environmentally sustainable technologies are adopted.
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